Thermochromic Pixel Color Locking via UV and Heat

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Solution Overview

Problem

Thermochromic materials used for forming multi-colored images on substrates face challenges in maintaining color stability, especially when exposed to intense short-wavelength UV illumination, leading to color shifts and instability.

Innovation Solution

A method involving the concurrent application of UV radiation and heat to thermochromic material pixels, where the pixels are initially heated to activate color shift and then exposed to a second UV radiation dosage at higher temperatures to stabilize the colors, ensuring long-term color retention and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If thermochromic material is exposed to intense short-wavelength UV illumination to form multi-colored images, then color change and image formation is achieved, but color stability deteriorates leading to color shifts and instability

Engineering Contradiction:
ImproveUV radiation dosageVSAvoidcolor stability
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent segments the UV exposure process into multiple distinct dosage levels applied at different temperatures. Instead of a single high-dosage exposure that causes color instability, the method divides the total UV exposure into at least two separate dosages: a first dosage applied at a first temperature to achieve initial color change, and a second dosage applied at a second temperature to stabilize the color. This segmentation allows each exposure step to serve a specific function, preventing the color instability that would result from a single intense exposure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes multiple parameters simultaneously to resolve the contradiction: it varies both the UV radiation dosage and the temperature at which exposure occurs. By applying different dosages at different temperatures, the method optimizes both color formation and stability. The first dosage at the first temperature produces the desired color change, while the second dosage at the second temperature locks in and stabilizes that color, preventing subsequent shifts under continued UV exposure.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If multiple UV radiation dosages are applied at different temperatures, then color stability is improved, but process complexity increases

Engineering Contradiction:
Improvecolor stabilityVSAvoidprocess complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent applies a preliminary UV radiation dosage at a specific temperature before finalizing the color. This first dosage prepares the thermochromic material by inducing an initial color change and setting it up for the subsequent stabilization step. By performing this preliminary action, the material is pre-conditioned to respond optimally to the second dosage, ensuring better color stability without requiring complex real-time adjustments during the process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs periodic action by applying UV radiation in distinct, separated dosages rather than as a continuous single exposure. The process involves at least two separate UV exposure events with potentially different dosages and temperatures, allowing the material to undergo controlled changes at each stage. This periodic application of energy enables better control over the color formation and stabilization processes, achieving superior color stability through structured, repeated actions rather than a single complex exposure.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in stable, locked colors with superior color stability under UV exposure, maintaining color integrity even after accelerated aging and environmental testing, as demonstrated by minimal ΔE values.

Implementation Method 1

Thermochromic materials change color in response to exposure to temperature and light

Methodology Applied
Scientific EffectThermochromism: Thermochromism

Implementation Method 2

the areas are exposed to heat and light to produce a color change in precisely controlled regions

Methodology Applied
Scientific EffectPhotochromism: Photochromism

Implementation Method 3

a first UV radiation dosage sufficient to at least partially polymerize the thermochromic material

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentEP3663097B1Method and system for producing stable locked colors in thermochromic materials
Publication Date: 2023.09.20 PALO ALTO RESEARCH CENTER INC
  • EP3663097B1 patent drawingFigure 1
  • EP3663097B1 patent drawingFigure 2A
  • EP3663097B1 patent drawingFigure 2B

AI summary

A method of forming a multi-colored image on a substrate that includes a thermochromic material capable of producing at least two different colors is disclosed. The method includes heating individually selected pixels of the thermochromic material that correspond to the image to one or more first temperatures sufficient to activate the selected pixels of the thermochromic material for color shift. The area corresponding to the individually selected pixels is flooded with a first UV radiation dosage sufficient to at least partially polymerize the thermochromic material. The individually selected pixels are heated to one or more second temperatures while the area is flooded with a second UV radiation dosage.