Thermochromic Stamp Ink Composition for High-Temperature Stability

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Solution Overview

Problem

Reversibly thermochromic stamps face issues with image decoloration due to unintended heating, blurring, and uneven ink discharge, especially when used in high temperature environments and with continuous pore stamp materials, leading to poor image quality and impractical successive stamping.

Innovation Solution

An ink composition for reversibly thermochromic stamps containing a reversibly thermochromic microencapsulated pigment with a specific temperature-dependent hue change, combined with a thickener and water, ensuring stable viscosity and thixotropy, and a stamp material with optimized pore structure for ink impregnation, maintaining image coloration in high temperatures and enabling clear, sharp, and consistent stamping.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a reversibly thermochromic microencapsulated pigment is used for the stamp ink, then the stamp image can be decolored by heating for erasing, but the image may decolor unintentionally in high temperature environments

Engineering Contradiction:
Improveerasing functionVSAvoidimage stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent adjusts the temperature characteristics of the reversibly thermochromic composition by selecting specific components (A, B, and C) with appropriate melting points and reaction temperatures. The composition is designed to remain stable at ambient temperatures while activating only when heated above a certain threshold, thus distinguishing between intentional erasing and unintentional decoloration.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a specific reaction medium (Component C) that acts as an intermediary between the electron-donating compound (A) and electron-accepting compound (B). This mediator controls the temperature at which the coloring reaction occurs, preventing premature decoloration while enabling controlled erasing when heated.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If the ink composition is used with a stamp material having continuous pores, then successive stamping is enabled, but the ink composition flowability becomes insufficient and image quality deteriorates

Engineering Contradiction:
Improvesuccessive stamping capabilityVSAvoidimage quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent modifies the physical parameters of the ink composition by adjusting viscosity, surface tension, and flow characteristics. The ink formulation includes specific additives and concentration levels that optimize flowability through continuous pores while maintaining adequate pigment loading for high-quality images during successive stamping operations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink composition combining the reversibly thermochromic microencapsulated pigment with specific carriers, binders, and additives. This composite formulation ensures proper flow dynamics through continuous pores while maintaining pigment dispersion and transfer quality for clear stamp images.

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If the ink composition viscosity is reduced to improve flowability, then ink supply to the stamp face improves, but the ink composition may blur and discharge becomes uneven

Engineering Contradiction:
Improveink flowabilityVSAvoiddischarge uniformity
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent optimizes the viscosity parameter of the ink composition to a specific range that balances flowability with discharge control. By adjusting viscosity, the ink flows sufficiently through continuous pores for successive stamping while maintaining enough coherence to prevent blurring and ensure uniform discharge patterns.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces thixotropic properties to the ink composition, making its viscosity dynamic rather than static. The ink exhibits lower viscosity during application to facilitate flow through pores, then thickens during stamping to prevent blurring and ensure uniform discharge, adapting its rheological properties to the operational requirements at different stages.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution prevents image decoloration in high temperatures, ensures clear and sharp stamp images, and facilitates smooth, consistent ink flow, maintaining image quality and practicality even in high temperature environments and with continuous pore stamp materials.

Implementation Method 1

Component (C): a reaction medium causing reversibly an electron transfer reaction between the Component (A) and the Component (B) in a specific temperature range

Methodology Applied
Scientific EffectElectron transfer reaction: Redox Reactions

Implementation Method 2

a reversibly thermochromic microencapsulated pigment encapsulating a reversibly thermochromic composition

Methodology Applied
Scientific EffectThermochromism: Thermochromism

Implementation Method 3

water; and a thickener

Methodology Applied
Scientific EffectThickening:

Implementation Method 4

a stamp material having continuous pores using an ink composition

Methodology Applied
Scientific EffectThixotropy: Thixotropy

Data Source

PatentEP3135738B1Ink composition for reversibly thermochromic stamps and stamp
Publication Date: 2021.11.03 PILOT PEN CO LTD
  • EP3135738B1 patent drawingFigure 1~2
  • EP3135738B1 patent drawingFigure 3~4
  • EP3135738B1 patent drawingFigure 5~6

AI summary

The invention provides an ink composition for a reversibly thermochromic stamp, a stamp image of which does not decolor even when the same is left to stand in a high temperature environment, and a stamp containing the same. [Solution] An ink composition for a reversibly thermochromic stamp including a reversibly thermochromic microencapsulated pigment encapsulating a reversibly thermochromic composition including: Component (A): an electron-donating color-developing organic compound, Component (B): an electron-accepting compound, and Component (C): a reaction medium causing reversibly an electron transfer reaction between the Component (A) and the Component (B) in a specific temperature range, water and a thickener, wherein: the reversibly thermochromic composition exhibits a 1st hue at a temperature t1, and exhibits a 2nd hue at a temperature t4 higher than the temperature t1, and coloring can be altered reciprocally between the 1st hue and the 2nd hue by changing the temperature; the reversibly thermochromic composition exhibiting the 1st hue at the temperature t1 starts color change at a temperature t3, when the temperature is elevated, and exhibits completely the 2nd hue in a temperature range not lower than the temperature t4 higher than the temperature t3, the reversibly thermochromic composition exhibiting the 2nd hue at the temperature t4 starts color change at a temperature t2, when the composition is cooled, and exhibits completely the 1st hue in a temperature range not higher than the temperature t1 lower than the temperature t2, a hysteresis property to keep the 1st hue or the 2nd hue in a temperature range between the temperature t2 and the temperature t3 is indicated, and the temperature t2 is a temperature not higher than 15°C, and the temperature t4 is a temperature not lower than 80°C.