Thermoelectric Module Sealing via Solid-Liquid Interdiffusion Bonding

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Solution Overview

Problem

Existing methods for manufacturing high-temperature thermoelectric modules using CoSb3-based skutterudite materials face challenges in achieving a cost-effective and reliable sealing process, particularly due to the materials' sensitivity to oxidation and the need for complex bonding techniques that are not easily scalable.

Innovation Solution

A method involving solid-liquid interdiffusion bonding (SLID) with an adhesion layer/diffusion barrier layer/adhesion layer (ADA) structure is employed to form both electrical contacts and a hermetic seal in a single process step, using metal layers that react to form intermetallic compounds at high temperatures, ensuring strong mechanical and gas-tight bonding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If complex bonding techniques are used to achieve reliable sealing, then sealing reliability is improved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvesealing reliabilityVSAvoidbonding process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple functions (electrical contact formation, thermal connection, and hermetic sealing) into a single integrated metal layer structure that performs all three functions simultaneously, eliminating the need for separate bonding processes for each function

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The metal layer is designed to serve multiple purposes: providing electrical conductivity for current flow, thermal conductivity for heat transfer, and hermetic sealing for oxidation protection, making it a multi-functional component that simplifies the overall device architecture

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Manufacturing precision

If multiple separate processes are used for electrical contact and sealing, then functional precision is improved, but manufacturing time and cost increase

Engineering Contradiction:
Improveelectrical contact precisionVSAvoidmanufacturing throughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent merges the electrical contact formation and hermetic sealing operations into a single simultaneous process step, where one metal layer formation process accomplishes both functions, thereby doubling manufacturing throughput without sacrificing precision

Inventive Principle:
Principle #5Merging (Combining)

3Ease of manufacture

If simple sealing methods are used, then manufacturing cost is reduced, but oxidation protection and reliability deteriorate

Engineering Contradiction:
Improvesealing process simplicityVSAvoidoxidation resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The metal layer is designed to simultaneously provide hermetic sealing for oxidation protection and maintain electrical and thermal conductivity, achieving reliable protection without requiring complex multi-layer sealing structures or additional protective coatings

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a cost-effective, resilient, and hermetically sealed thermoelectric module capable of operating at high temperatures (up to 700-800°C) with improved bonding strength and reduced material degradation, enhancing the module's reliability and efficiency.

Implementation Method 1

solid-liquid interdiffusion bonding (SLID) with an adhesion layer/diffusion barrier layer/adhesion layer (ADA) structure is employed to form both electrical contacts and a hermetic seal

Methodology Applied
Scientific EffectSolid-liquid interdiffusion bonding: Diffusion

Implementation Method 2

metal layers that react to form intermetallic compounds at high temperatures, ensuring strong mechanical and gas-tight bonding

Methodology Applied
Scientific EffectIntermetallic compound formation: Chemical Bonding

Implementation Method 3

The Seebeck effect is one of three possible expressions of the thermoelectric effect, namely the direct conversion of thermal energy to electric energy found in some materials when subject to a temperature gradient creating a heat flux through the material

Methodology Applied
Scientific EffectSeebeck effect: Seebeck Effect

Implementation Method 4

adhesion layer/diffusion barrier layer/adhesion layer (ADA) structure

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 5

adhesion layer/diffusion barrier layer/adhesion layer (ADA) structure

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS10468576B2Method of manufacturing a sealed thermoelectric module
Publication Date: 2019.11.05 TEGMA
  • US10468576B2 patent drawing
  • US10468576B2 patent drawing
  • US10468576B2 patent drawing

AI summary

A method for manufacturing a thermoelectric module utilizes solid-liquid interdiffusion bonding for both forming metallization, interconnection and bonding between thermoelectric elements and electric contacts and forming of a hermetic sealing of the thermoelectric module.