Thermolysis Waste Plastics Apparatus with Two-Step Separation

Solution Overview

Problem

Current methods for thermolysis of plastic waste struggle with achieving efficient and repeatable production of high-quality hydrocarbon products while minimizing energy consumption and unwanted byproducts like coke, and often require catalysts or complex separation processes.

Innovation Solution

A continuous thermolysis process using an extruder to plasticize waste plastics, which are then fed into a reactor with dual high-speed propellers, operating at 390-430°C, with a two-step product separation system involving direct contact condensers and wiped film evaporators, allowing for the production of three distinct hydrocarbon fractions without catalysts and reducing coke formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If catalysts are used in thermolysis process, then hydrocarbon production efficiency is improved, but process complexity and cost increase

Engineering Contradiction:
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention extracts and removes the catalyst component from the thermolysis process. By conducting catalytic cracking without physical catalysts present in the reactor, the process eliminates catalyst handling, separation, and regeneration complexities while maintaining high hydrocarbon production efficiency through vapor-phase catalytic cracking.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention introduces a circulating fluidized bed as an intermediary system that enables catalytic cracking without direct catalyst contact in the main reactor. The circulating fluidized bed acts as a mediator that facilitates hydrocarbon production while allowing continuous catalyst circulation and regeneration outside the main reaction zone.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If thermolysis temperature is increased to improve hydrocarbon yield, then production efficiency increases, but energy consumption and coke formation increase

Engineering Contradiction:
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The invention changes the operational parameters by conducting thermolysis at moderate temperatures (300-450°C) rather than high temperatures, while maintaining high hydrocarbon yield through the introduction of catalysts and use of circulating fluidized bed technology that enhances reaction efficiency at lower energy input.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The circulating fluidized bed enables continuous catalyst circulation and regeneration, maintaining optimal catalytic activity throughout the process. This continuous action ensures sustained high hydrocarbon yield without requiring temperature increases that would raise energy consumption and coke formation.

Inventive Principle:
Principle #20Continuity of useful action

3Manufacturing precision

If complex separation processes are used to purify hydrocarbon products, then product quality is improved, but process complexity and production time increase

Engineering Contradiction:
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention segments the product separation into distinct fractional distillation stages that separate hydrocarbons by boiling point ranges. This segmentation achieves high product quality through systematic fractionation while keeping each separation stage relatively simple and manageable.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes separation parameters by using fractional distillation based on boiling point differences rather than complex chemical separation methods. This approach achieves high product purity through physical property differences, simplifying the separation process while maintaining manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If continuous thermolysis process is implemented, then productivity is improved, but process control complexity and equipment requirements increase

Engineering Contradiction:
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention implements continuous thermolysis through a circulating fluidized bed system that enables uninterrupted feedstock processing and product formation. The continuous circulation of catalyst and maintainance of steady-state operation ensure continuous hydrocarbon production while using relatively simple control mechanisms.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The circulating fluidized bed system provides self-regulating characteristics where the fluidization process automatically maintains optimal mixing and heat transfer conditions. The system self-adjusts to maintain continuous operation without requiring complex external control mechanisms, achieving high productivity with simplified process control.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of high-repeatability light oil, heavy oil, and wax products with reduced energy consumption and minimal unwanted byproducts, allowing for flexible processing and direct commercialization or further refining of products, with the gaseous product usable as fuel for process heating.

Implementation Method 1

plastic waste are continuously fed to the extruder where are plasticized

Methodology Applied
Scientific EffectPlasticization:

Implementation Method 2

heated up to the temperature of the reactor

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

in temperature 380 - 500 °C polymeric chains' cracking and producing light hydrocarbons takes place

Methodology Applied
Scientific EffectThermolysis: Thermolysis

Implementation Method 4

polymeric chains' cracking and producing light hydrocarbons

Methodology Applied
Scientific EffectCracking: Pyrolysis

Implementation Method 5

vapor-liquid mixture is transported to separator from which the liquid phase is returned into cracking reactor and gaseous phase is conducted to water-cooled condenser

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 6

The liquid phase is separated on gasoline fraction conducted into tank and diesel oil conducted into tank in distillation column

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 7

dual high-speed propellers, allowing for the production of three distinct hydrocarbon fractions

Methodology Applied
Scientific EffectMechanical mixing: Stirring

Implementation Method 8

two-step product separation system involving direct contact condensers and wiped film evaporators

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 9

two-step product separation system involving direct contact condensers and wiped film evaporators

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentEP2417223B1Apparatus for thermolysis waste plastics and method for thermolysis waste plastics
Publication Date: 2019.02.06
  • EP2417223B1 patent drawingFigure 1

AI summary

The subject of the invention is apparatus and method for thermolysis of waste plastics especially for receiving of hydrocarbon products. Apparatus for thermolysis of waste plastics consisting feeding system, thermolysis reactor, external circulation loop and product collecting system according to the invention is characterized in that collecting and two-step product separation system is involving condenser (6), product cooling system (3), light fraction receiver (26) with gaseous product removing system (27), crude heavy fraction receiver (21) and vacuum evaporator (7). Plastic waste thermolysis method is characterized in that product vapors are removed continuously from reactor and conducted to condenser in which condensation of vapors is carried out and product mixture separation to light oil conducted to light oil receiver from which the gaseous products are received and liquid products are conducted to light oil tank and for further processing and crude heavy which through heat exchanger and crude heavy oil receiver is pumped to vacuum evaporator in which next step of separation of crude heavy oil to and heavy oil is obtained.