Thermoplastic Elastomer Inner Liner Reducing Extrusion Load
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Solution Overview
Problem
Pneumatic tires with ethylene-vinyl alcohol copolymer inner liners face insufficient low-temperature impact resistance and high extrusion loads during molding, which need to be improved without compromising durability.
Innovation Solution
A thermoplastic elastomer composition is developed, where modified rubber with acid anhydride or epoxy groups is dynamically cross-linked using compounds with multiple amino groups, particularly diaminodiphenyl disulfide and diaminodiphenyl sulfone, and dispersed in an ethylene-vinyl alcohol copolymer matrix, optimizing the ratio and cross-linking to reduce extrusion loads while maintaining low-temperature durability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If modified rubber is dispersed in ethylene-vinyl alcohol copolymer to improve low-temperature durability, then low-temperature impact resistance is improved, but extrusion load during extrusion molding increases
Solution Approach 1:
The patent applies parameter changes by introducing dynamic cross-linking of modified rubber using compounds with amino groups and disulfide bonds. This chemical modification changes the rheological parameters of the rubber phase, enabling it to maintain low-temperature durability while reducing extrusion load through reversible cross-linking that breaks down under extrusion heat and pressure
Solution Approach 2:
The patent creates a composite material system where modified rubber with specific functional groups (amino groups and disulfide bonds) is dispersed in an ethylene-vinyl alcohol copolymer matrix. The composite structure allows the rubber particles to provide low-temperature toughness while the matrix provides gas barrier properties, and the dynamic cross-linking mechanism reduces processing resistance during extrusion
2Strength
If crosslinkable rubber is admixed into ethylene-vinyl alcohol copolymer to improve impact resistance, then low-temperature impact resistance is improved, but manufacturing complexity increases
Solution Approach 1:
The patent uses compounds containing both amino groups and disulfide bonds as intermediary agents that facilitate dynamic cross-linking between modified rubber particles. These intermediary compounds enable the cross-linking reaction to occur under extrusion conditions, simplifying the manufacturing process by eliminating separate cross-linking steps while maintaining impact resistance
Solution Approach 2:
The patent introduces dynamic cross-linking where the cross-link bonds can form and break reversibly under different conditions. During storage, cross-links provide structural integrity for impact resistance; during extrusion, the bonds break under heat and pressure, reducing viscosity and extrusion load, then reform after extrusion to maintain durability
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution effectively reduces extrusion loads during molding while maintaining or enhancing low-temperature durability, as demonstrated by improved melt viscosity, extrusion load indices, and repeated deformation resistance at -35°C.
Implementation Method 1
the modified rubber (B) is dynamically cross-linked by a compound (C) having at least two amino groups
Implementation Method 2
extrusion molding thereof into a film
Data Source
AI summary
An object of the present invention is, in a thermoplastic elastomer composition in which a modified rubber is dispersed and filled in an ethylene-vinyl alcohol copolymer matrix in order to improve the low-temperature durability of the ethylene-vinyl alcohol copolymer, to reduce the extrusion load during extrusion molding thereof into a film without deteriorating the low-temperature durability. The present invention is a thermoplastic elastomer composition comprising an ethylene-vinyl alcohol copolymer (A) and a modified rubber (B) dispersed in the ethylene-vinyl alcohol copolymer (A), wherein the modified rubber (B) has an acid anhydride group or epoxy group and is dynamically cross-linked by a compound (C) having at least two amino groups. This thermoplastic elastomer composition can be suitably used in the production of an inner liner of a pneumatic tire.


