Thermoplastic Elastomer Stabilized Thixotropic Serum Separation

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Solution Overview

Problem

Thixotropic serum- or plasma-separating compositions used in blood centrifugation tend to undergo phase separation due to strong hydrogen bonding, leading to localization of components and leakage, which contaminates measurement devices and affects measurement precision.

Innovation Solution

Incorporating a thermoplastic elastomer into the composition with a liquid organic compound and a thixotropic-property imparting component, such as a styrene-based thermoplastic elastomer, to maintain a homogeneously blended state and prevent phase separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a thixotropic-property imparting component is used to form a hydrogen-bonding-based network in a liquid organic compound, then thixotropic property is achieved, but phase separation occurs over time due to strong aggregation

Engineering Contradiction:
Improvethixotropic property stabilityVSAvoidcompositional homogeneity
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

A silane-modified polyoxyethylene compound is introduced as an intermediary substance between the thixotropic-property imparting component and the liquid organic compound. This intermediary prevents direct strong hydrogen bonding that causes aggregation, while still enabling thixotropic property development, thus maintaining compositional homogeneity over time

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention modifies the chemical parameters of the thixotropic-property imparting component by introducing silane modification to the polyoxyethylene compound. This parameter change alters the hydrogen bonding characteristics, reducing excessive aggregation tendency while preserving the ability to form a thixotropic network structure

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If phase separation occurs in the serum- or plasma-separating composition, then liquid organic compound leaks and spreads, but this contaminates measurement devices and affects measurement precision

Engineering Contradiction:
Improvecomposition fluidityVSAvoidmeasurement accuracy
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The silane-modified polyoxyethylene compound acts as a mediator that maintains controlled fluidity while preventing uncontrolled spreading. It regulates the interaction between components to ensure the composition remains fluid enough for operation but stable enough to prevent contamination

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By modifying the polyoxyethylene compound with silane groups, the invention changes the surface properties and hydrogen bonding capacity, thereby controlling the fluidity and spreading characteristics of the liquid organic compound to prevent device contamination

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents separation between the liquid organic compound and the thixotropic-property imparting component, maintaining homogeneity even at high temperatures, thus preventing contamination and ensuring precise measurement of serum or plasma components.

Implementation Method 1

The thixotropic-property imparting agent and the thixotropic-property enhancer disclosed in Patent Literatures 1 and 2 are intended to obtain a thixotropic-property by forming a hydrogen-bonding-based network in a liquid organic compound.

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Implementation Method 2

techniques for separating serum or plasma from blood by centrifugation using a difference in the specific gravities between blood components are widely used

Methodology Applied
Scientific EffectCentrifugal separation: Centrifugal Separation

Data Source

PatentEP3309547B1Serum- or plasma-separating composition, blood-test container, and method of stabilizing serum- or plasma-separating composition
Publication Date: 2020.10.14 SEKISUI MEDICAL CO LTD

AI summary

There is provided a serum- or plasma-separating composition less likely to cause separation between a liquid organic compound and a thixotropy imparting component and capable of maintaining a homogeneous blended state for a prolonged period. The serum- or plasma-separating composition comprises a liquid organic compound, a thixotropy imparting component, and a thermoplastic elastomer.