Oil-Soluble Thermosensitive Resin Lost Circulation Material

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Solution Overview

Problem

Conventional lost circulation materials exhibit weak performance in plugging large fractures and caves due to insufficient temperature resistance and pressure bearing, leading to secondary leakage and reduced oil and gas recovery efficiency.

Innovation Solution

An oil-soluble thermosensitive resin lost circulation material composed of 40-60 parts resin matrix, 15-40 parts modified asphalt, 5-12 parts viscosity modifier, 2-5 parts cross-linking agent, and 1-3 parts dispersant, which can melt and adhere at various temperatures, forming a plugging layer with high adhesion and elasticity, and is fully dissolved in crude oil for reservoir protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional plugging materials (walnut shell, mica) are used, then the material can be easily obtained and applied, but the temperature resistance and pressure bearing are insufficient, leading to poor plugging performance in large fractures

Engineering Contradiction:
Improveplugging strengthVSAvoidmaterial complexity
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent uses a composite material system comprising thermosensitive resin, asphalt, coupling agent, and filler. This composite structure combines the high-temperature resistance of thermosensitive resin, the adhesion and flexibility of asphalt, and the bulk properties of filler, achieving superior plugging strength in large fractures while maintaining ease of application.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs thermosensitive resin that undergoes parameter changes (phase transition from solid to liquid) in response to temperature variations. This allows the material to adapt its properties to match formation conditions, providing effective plugging under high temperature and pressure while maintaining ease of injection during drilling operations.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If gel lost circulation materials are used, then the material can adapt to pore size, but the temperature and salt resistance are poor and mechanical strength is low

Engineering Contradiction:
Improvepore size adaptationVSAvoidtemperature and salt resistance
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent creates a composite system where thermosensitive resin provides temperature resistance, asphalt contributes to salt resistance and flexibility, and the combination maintains adaptability to pore sizes. This composite approach solves the reliability issues of gel materials while preserving their adaptability advantage.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses coupling agents to provide local quality enhancement at the interface between the plugging material and formation. This improves adhesion and reliability in specific critical zones while maintaining overall material adaptability to different pore structures.

Inventive Principle:
Principle #3Local quality

3Duration of action of moving object

If oil-soluble thermosensitive resin lost circulation material is used, then rapid fracture plugging with long plugging time is achieved, but the oil soluble rate is low and oil solubility at high temperature is poor

Engineering Contradiction:
Improveplugging timeVSAvoidoil solubility
Core Design Contradiction:
Duration of action of moving objectVSEase of manufacture

Solution Approach 1:

The patent combines thermosensitive resin with asphalt and coupling agents to create a composite material that maintains excellent oil solubility and high-temperature solubility. The asphalt component specifically enhances oil compatibility, ensuring rapid dissolution and reservoir protection while the thermosensitive resin provides long plugging duration.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The coupling agent acts as an intermediary that improves the interaction between the resin matrix and oil, enhancing oil solubility and dissolution rate. This mediator allows the material to achieve both long plugging time and excellent oil compatibility without compromising either property.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Strength

If existing oil-soluble lost circulation materials are used, then some plugging function is achieved, but the plugging strength is low and adaptive temperature range is narrow

Engineering Contradiction:
Improveplugging strengthVSAvoidtemperature range
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent utilizes thermosensitive resin that undergoes parameter changes (melting point transition) in response to temperature variations. This allows the material to adapt to a wide temperature range, providing effective plugging from moderate to high temperature formations while maintaining high plugging strength through controlled phase transitions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite formulation combines thermosensitive resin with asphalt and fillers in specific ratios to achieve both high plugging strength and broad temperature adaptability. The synergistic interaction of components expands the usable temperature range while enhancing overall plugging performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material achieves effective plugging of fractures with high pressure bearing capacity, long plugging time, and excellent oil solubility, recovering reservoir permeability and preventing repeated leakage, while being simple to produce and integrate into drilling operations.

Implementation Method 1

the oil-soluble thermosensitive resin lost circulation material can melt and adhere at various temperature ranges

Methodology Applied
Scientific EffectThermosensitive melting: Melting

Implementation Method 2

forming a plugging layer with high adhesion and elasticity

Methodology Applied
Scientific EffectThermal adhesion: Adhesive

Implementation Method 3

the oil-soluble resin lost circulation material can be dissolved by oil flow during oil well production because of the characteristic that the oil-soluble resin is oil-soluble

Methodology Applied
Scientific EffectOil solubility: Solvation

Data Source

PatentUS12043742B2Oil-soluble thermosensitive resin lost circulation material for protecting a reservoir as well as preparation method and application thereof
Publication Date: 2024.07.23 CHINA UNIV OF PETROLEUM (EAST CHINA)
  • US12043742B2 patent drawing

AI summary

An oil-soluble thermosensitive resin lost circulation material for protecting a reservoir includes the following raw materials in parts by weight: 40-60 parts of resin matrix, 15-40 parts of modified asphalt, 5-12 parts of viscosity modifier, 2-5 parts of cross-linking agent, 6-15 parts of softening point modifier, and 1-3 parts of dispersant; it further provides a method for preparing the resin lost circulation material; the resin lost circulation material can melt and adhere in different temperature ranges, rapid plugging is realized, and the plugging time is long; the oil-soluble thermosensitive resin lost circulation material can be dissolved by oil flow during oil well production, so that the reservoir permeability is recovered, so as to achieve the purpose of protecting the hydrocarbon reservoir.