Thiazole Electrolyte Composition for Secondary Battery Cyclability

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Solution Overview

Problem

Existing secondary batteries do not achieve sufficient battery characteristics, indicating a need for improvement in their performance.

Innovation Solution

Incorporating a thiazole-type compound, specifically represented by Formulas (1) and (2), into the electrolytic solution of secondary batteries, which forms a dense and electrochemically stable film on the negative electrode, thereby suppressing decomposition reactions and maintaining discharge capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrolytic solutions are used, then the battery structure is simple, but the battery characteristic is insufficient

Engineering Contradiction:
Improvebattery characteristicVSAvoidelectrolytic solution composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite electrolytic solution formulation by combining multiple thiazole-type compounds (Formula 1 and Formula 2) with specific functional groups. This composite approach creates synergistic effects that improve battery characteristics including discharge capacity and cyclability, while the structured combination maintains manageable complexity through targeted molecular design.

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If thiazole-type compounds are added to improve battery characteristics, then discharge capacity is maintained, but electrolytic solution complexity increases

Engineering Contradiction:
Improvedischarge capacityVSAvoidelectrolytic solution structure
Core Design Contradiction:
Duration of action of moving objectVSDevice complexity

Solution Approach 1:

The patent systematically varies molecular parameters of thiazole-type compounds including substituent groups (R1-R15), molecular weight, and functional group configurations. By optimizing these parameters within specific ranges, the invention achieves improved discharge capacity and cyclability while controlling electrolytic solution complexity through parameter optimization rather than indiscriminate component addition.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If conventional electrolytes are used, then manufacturing is simple, but cyclability deteriorates after repeated charging and discharging

Engineering Contradiction:
ImprovecyclabilityVSAvoidelectrolytic solution preparation
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The thiazole-type compounds in the electrolytic solution perform preliminary protective action by forming stable interface films on electrode surfaces before degradation occurs. This preliminary film formation prevents subsequent decomposition reactions during repeated charging and discharging, thereby improving cyclability. The manufacturing process remains relatively simple as it involves standard electrolyte preparation procedures.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of thiazole-type compounds in the electrolytic solution enhances the battery characteristics of secondary batteries by maintaining discharge capacity and improving cyclability, even after repeated charging and discharging.

Implementation Method 1

forms a dense and electrochemically stable film on the negative electrode

Methodology Applied
Scientific EffectFilm formation: Deposition (physical)

Implementation Method 2

electrochemically stable film

Methodology Applied
Scientific EffectElectrochemical stability: Electrochemiluminescence

Implementation Method 3

suppressing decomposition reactions and maintaining discharge capacity

Methodology Applied
Scientific EffectDecomposition suppression: Decomposition (biological)

Data Source

PatentUS20250201925A1Electrolytic solution for secondary battery, and secondary battery
Publication Date: 2025.06.19 MURATA MFG CO LTD
  • US20250201925A1 patent drawing
  • US20250201925A1 patent drawing
  • US20250201925A1 patent drawing

AI summary

A secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The electrolytic solution includes a thiazole-type compound. The thiazole-type compound includes a compound represented by Formula (1), a compound represented by Formula (2), or both.