Thickened Resist Pattern Layering for Resolution and Mask Durability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for manufacturing resist patterns face challenges in thickening fine patterns, achieving sufficient resolution with increased numerical aperture, maintaining pattern shape integrity, and widening the process window, especially in high-definition lithography where resist film thickness affects durability and etching mask performance.

Innovation Solution

A method involving the application of a resist composition followed by exposure and then a thickening solution comprising a polymer and solvent to form a thickening layer before development, which enhances resist film thickness and durability, allowing for improved resolution and process window stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the resist film thickness is increased to improve durability as an etching mask, then the mask durability is improved, but the process window becomes narrower and pattern collapse is more likely to occur

Engineering Contradiction:
Improvemask durabilityVSAvoidprocess window
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent divides the resist system into two separate layers: a thin resist layer (5-20 nm) for pattern formation and a thick thickening layer (5-50 nm) for mask durability. This segmentation allows each layer to perform its specific function optimally without the trade-offs of using a single thick resist layer, thereby resolving the contradiction between mask durability and process window.

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If the resist film thickness is decreased to widen the process window, then the process window is widened, but the mask durability is insufficient and the substrate may be scraped during etching

Engineering Contradiction:
Improveprocess windowVSAvoidmask durability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent divides the resist system into two separate layers: a thin resist layer (5-20 nm) for pattern formation and a thick thickening layer (5-50 nm) for mask durability. This segmentation allows each layer to perform its specific function optimally without the trade-offs of using a single thick resist layer, thereby resolving the contradiction between mask durability and process window.

Inventive Principle:
Principle #1Segmentation

3Reliability

If a thick resist layer is used to ensure mask durability, then the mask durability is improved, but the resolution and pattern shape control become more difficult

Engineering Contradiction:
Improvemask durabilityVSAvoidresolution
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent divides the resist system into two separate layers: a thin resist layer (5-20 nm) for pattern formation and a thick thickening layer (5-50 nm) for mask durability. This segmentation allows each layer to perform its specific function optimally without the trade-offs of using a single thick resist layer, thereby resolving the contradiction between mask durability and process window.

Inventive Principle:
Principle #1Segmentation

4Reliability

If the resist film is thickened to improve etching mask performance, then the etching resistance is improved, but the pattern shape integrity deteriorates due to focus and exposure amount shifts

Engineering Contradiction:
Improveetching resistanceVSAvoidpattern shape integrity
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent divides the resist system into two separate layers: a thin resist layer (5-20 nm) for pattern formation and a thick thickening layer (5-50 nm) for mask durability. This segmentation allows each layer to perform its specific function optimally without the trade-offs of using a single thick resist layer, thereby resolving the contradiction between mask durability and process window.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively thickens resist patterns, enhances their durability as etching masks, and widens the process window, improving manufacturing yield and pattern integrity in high-definition lithography.

Implementation Method 1

a chemically amplified resist composition, and more specifically, a PHS-acrylate hybrid-based chemically amplified resist composition

Methodology Applied
Scientific EffectPhotoacid generator reaction: Photo-oxidation

Data Source

PatentUS20240036469A1Method for manufacturing thickened resist pattern, thickening solution, and method for manufacturing processed substrate
Publication Date: 2024.02.01 MERCK PATENT GMBH
  • US20240036469A1 patent drawing
  • US20240036469A1 patent drawing
  • US20240036469A1 patent drawing

AI summary

[Problem] To provide a method for manufacturing a thickened resist pattern. [Means for Solution] A method for manufacturing a thickened resist pattern comprising the following steps: (1) applying a resist composition above a substrate to form a resist layer from the resist composition; (2a) exposing the resist layer; (2b) applying a thickening solution comprising a polymer (A) and a solvent (B) on the resist layer to form a thickening layer; and (3) developing the resist layer and the thickening layer.