Thin Film Deposition Apparatus with Segmented Gas Flow Control

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Solution Overview

Problem

Conventional thin film deposition apparatuses struggle to achieve commercially viable deposition rates and desired properties, particularly in on-line coating processes for glass substrates, where high temperatures and short chemical reaction times are required, and off-line sputtering processes result in more complex but expensive films.

Innovation Solution

The apparatus maintains discrete gaseous reactant flow paths to ensure reactants mix and react at the substrate surface, using slot-like outlet openings and gas flow conditioning devices to control turbulence and uniformity, allowing for rapid and uniform film deposition at high rates suitable for solar control and conductive coatings.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional on-line deposition apparatus are used, then deposition can occur during glass manufacturing, but deposition rates are insufficient for commercial viability

Engineering Contradiction:
Improvedeposition rateVSAvoidfilm quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The apparatus segments the gas delivery system into multiple discrete slot-like outlets arranged in arrays, with each slot delivering reactants through controlled flow pathways. This segmentation enables precise control of reactant distribution across the substrate surface, achieving both high deposition rates and uniform film quality simultaneously

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the physical parameters of gas delivery by using slot-like outlets with specific dimensions and arrangements, controlling flow rates and velocities to optimize the balance between deposition rate and film uniformity. Temperature parameters are also controlled to achieve rapid deposition while maintaining film quality

Inventive Principle:
Principle #35Parameter changes

2Reliability

If off-line sputter coating processes are used, then complex film stacks with superior properties can be deposited, but production cost increases significantly

Engineering Contradiction:
Improvefilm propertiesVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention replaces the mechanical sputtering process with a chemical vapor deposition process using controlled reactant gas flows. This substitution eliminates the need for vacuum systems and target materials required in sputtering, significantly reducing equipment complexity and production costs while achieving comparable or superior film properties through chemical reactions at the substrate surface

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the deposition mechanism from physical sputtering to chemical vapor deposition, altering the fundamental parameters of the process. By controlling temperature, gas flow rates, and reactant concentrations, the process achieves complex film stacks with desired properties at lower costs than sputtering

Inventive Principle:
Principle #35Parameter changes

3Productivity

If reactant gases are delivered without discrete flow paths, then deposition can occur, but pre-reaction of reactants reduces deposition efficiency

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidflow path configuration
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The apparatus uses segmented discrete flow pathways that keep different reactant gases separated until they reach the substrate surface. Each slot-like outlet has dedicated flow paths that prevent premature mixing, ensuring reactants remain separate during delivery and only react at the deposition zone, maximizing deposition efficiency

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The slot-like outlets and flow pathways act as intermediaries that control and manage the delivery of reactant gases. These structures provide controlled environments that prevent pre-reaction while enabling efficient transport of reactants to the substrate surface where deposition occurs

Inventive Principle:
Principle #24Intermediary (Mediator)

4Productivity

If high deposition rates are achieved, then commercial viability is possible, but film uniformity deteriorates

Engineering Contradiction:
Improvedeposition rateVSAvoidfilm uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The segmented array of slot-like outlets distributes reactants uniformly across the substrate surface, with each slot contributing to a specific region. This segmented delivery system maintains consistent reactant flux across the entire substrate even at high deposition rates, ensuring uniform film thickness and properties throughout

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention optimizes multiple parameters including slot dimensions, spacing, gas flow rates, and substrate temperature to achieve the optimal balance between high deposition rate and film uniformity. By carefully controlling these parameters, the process maintains manufacturing precision while achieving commercially viable productivity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of thin films at commercially viable rates, exceeding 5 nm/sec, with excellent uniformity and desired properties for solar control and transparent conductive coatings, while preventing pre-reaction and maintaining thermal stability.

Implementation Method 1

chemical vapor deposition, most preferably by atmospheric chemical vapor deposition

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

establishing a second flow of a second reactant gas as a turbulent flow at an angle to the glass surface

Methodology Applied
Scientific EffectTurbulent flow: Turbulence

Implementation Method 3

Gas flow conditioning devices are placed in one or more of the flow paths between the at least one gaseous reactant inlet opening and the at least one gaseous reactant outlet opening

Methodology Applied
Scientific EffectFlow conditioning:

Data Source

PatentEP2688851B1Apparatus for depositing thin film coatings and method of deposition utilizing such apparatus
Publication Date: 2019.01.23 PILKINGTON GRP LTD
  • EP2688851B1 patent drawingFigure 1
  • EP2688851B1 patent drawingFigure 2
  • EP2688851B1 patent drawingFigure 3

AI summary

The invention relates to an apparatus for depositing thin film coatings on a substrate. The deposition apparatus is designed to keep gaseous reactant materials to be deposited apart from one another in the deposition apparatus, by one or more separation devices and/or methods, but nevertheless, to allow the chemical reactants to mix and react at or near the substrate surface, rapidly enough to create a uniform film at commercially viable deposition rates.