Thin-Wall Ceramic Coating via Carbon Substrate Combustion

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Solution Overview

Problem

Conventional methods for producing thin-wall ceramic or metal articles often result in cracking and warpage, leading to reduced yields and increased costs due to the need for thicker initial molding, longer processing times, and excessive material usage.

Innovation Solution

Thermally spraying ceramic or metal particles onto a carbon substrate of cylindrical or cup shape, followed by combustion treatment to burn out the carbon substrate, thereby creating a thin-wall sprayed coating without the need for molding and sintering steps.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional molding methods are used to produce thin-wall articles, then the article can be manufactured with standard processes, but cracking occurs during molding and sintering leading to reduced yield

Engineering Contradiction:
Improvewall thickness uniformityVSAvoidcracking during molding and sintering
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention applies preliminary action by pre-forming a green compact with controlled porosity distribution before sintering. The green compact is molded with a specific porous structure that prevents cracking during subsequent sintering, allowing thin-wall articles to be produced without the cracking issues that plague conventional methods.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention changes the physical parameters of the green compact by controlling its porosity and density distribution. The green compact is prepared with higher porosity in the wall regions, which reduces stress concentration during sintering and prevents cracking, while maintaining the desired final wall thickness.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If thicker compacts are molded to ensure higher yields, then compact formation success improves, but material usage increases and processing time extends

Engineering Contradiction:
Improvecompact formation yieldVSAvoidsource material consumption
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The invention changes the density and porosity parameters of the green compact to optimize both yield and material efficiency. By controlling the green compact to have non-uniform density distribution with higher porosity in wall regions, the process achieves high formation yield while using only the necessary amount of material, avoiding the waste associated with thicker initial molding.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The preliminary formation of a green compact with optimized porosity structure enables direct production of thin-wall articles without requiring excessive material. The green compact stage allows precise control of material distribution, ensuring that only the required amount of material is used while maintaining high formation yield.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If thicker compacts are molded to ensure higher yields, then compact formation success improves, but processing time increases due to longer sintering and machining required

Engineering Contradiction:
Improvecompact formation yieldVSAvoidsintering and machining time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention optimizes the sintering process parameters by controlling the green compact's porosity and density distribution. The pre-formed porous structure in the green compact allows for faster, more uniform sintering, reducing the time required while maintaining high formation yield and achieving the desired final wall thickness without extensive machining.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The preliminary formation of the green compact with controlled porosity structure prepares the material for efficient sintering. This pre-processing step ensures that the subsequent sintering occurs more rapidly and uniformly, reducing overall processing time while maintaining high yield, eliminating the need for time-consuming machining of thick walls.

Inventive Principle:
Principle #10Preliminary action

4Ease of manufacture

If standard molding methods are used, then the process is straightforward, but warpage occurs during sintering substantially reducing overall yield

Engineering Contradiction:
Improvemolding process simplicityVSAvoidwarpage during sintering
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The invention changes the physical parameters of the green compact, specifically its porosity and density distribution, to prevent warpage during sintering. The green compact is prepared with higher porosity in wall regions, which promotes uniform thermal and stress distribution during sintering, eliminating warpage while maintaining process simplicity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The preliminary formation of the green compact with optimized porosity structure prevents warpage before sintering occurs. This pre-control of material structure ensures uniform sintering behavior, maintaining dimensional accuracy and eliminating warpage issues without complicating the manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for the production of thin-wall articles with minimal warpage and deformation, reducing material waste and processing time, while providing articles with high inertness, heat resistance, abrasion resistance, corrosion resistance, and chemical resistance.

Implementation Method 1

thermally spraying ceramic particles of rare earth oxide or fluoride or metal particles of W, Mo or Ta onto a surface of a carbon substrate

Methodology Applied
Scientific EffectThermal spraying: Plasma Spray

Implementation Method 2

combustion treating the coated substrate to burn out the carbon substrate

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS10744673B2Sprayed article and making method
Publication Date: 2020.08.18 SHIN ETSU CHEMICAL CO LTD

AI summary

A sprayed article is prepared by thermally spraying ceramic particles of rare earth oxide or fluoride or metal particles of W, Mo or Ta onto an outer or inner surface of a cylindrical carbon substrate to form a sprayed coating, and burning out the carbon substrate, thus leaving the ceramic or metal-base sprayed coating of cylindrical shape having a wall thickness of 0.5-5 mm.