Thiolate salt melt additives

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Solution Overview

Problem

There is a need for electret webs with improved properties that can be easily charged through various mechanisms such as tribocharging, corona discharge, or hydrocharging, and can maintain enhanced filtration performance without requiring additional charging methods.

Innovation Solution

The development of electret webs comprising a blend of a thermoplastic resin and a charge-enhancing additive, specifically mercapto-benzothiazole or mercapto-benzoxazole metal salts, which allows for efficient charging via DC corona discharge alone, enhancing their filtration capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional thermoplastic resin webs are used for electret filtration, then the web structure is simple and easy to manufacture, but the charge retention and filtration performance are insufficient

Engineering Contradiction:
Improvecharge retentionVSAvoidweb composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining thermoplastic resin with charge-enhancing additives (mercaptobenzothiazole or mercapto-benzoxazole metal salts) to create an electret web that achieves both improved charge retention and acceptable manufacturing complexity. The composite formulation allows the web to exhibit superior electret properties while maintaining a manageable composition structure.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by modifying the chemical composition of the web through the addition of specific metal salts (divalent or trivalent) of mercapto-benzothiazole or mercapto-benzoxazole. These compositional parameter changes enable enhanced charge retention without fundamentally altering the web's structural parameters, thus balancing performance improvement with manufacturing feasibility.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If multiple charging methods are employed to enhance filtration performance, then the filtration efficiency improves, but the process complexity and time consumption increase

Engineering Contradiction:
Improvefiltration performanceVSAvoidcharging process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies self-service by designing a web composition that inherently responds to charging mechanisms. The charge-enhancing additives (mercaptobenzothiazole or mercapto-benzoxazole metal salts) enable the web to effectively utilize charging processes without requiring complex multi-step procedures. The composition itself facilitates efficient charge acquisition and retention through standard charging methods.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent uses parameter changes in the web's chemical composition to improve its responsiveness to charging processes. By incorporating specific metal salts, the web's electrical properties are modified, allowing it to achieve better filtration performance through simpler, more direct charging applications rather than requiring multiple complex charging steps.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If charge-enhancing additives are added to thermoplastic resin, then the electret properties are enhanced, but the manufacturing process becomes more complex

Engineering Contradiction:
Improveelectret charge retentionVSAvoidweb production
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies composite materials by formulating a blend of thermoplastic resin with charge-enhancing additives (mercaptobenzothiazole or mercapto-benzoxazole metal salts). This composite approach enhances electret charge retention while maintaining a relatively straightforward manufacturing process, as the additives are incorporated into the resin matrix during standard web production.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by adjusting the chemical composition of the web through controlled addition of metal salt additives. These compositional modifications are integrated into existing manufacturing processes, allowing enhanced electret properties to be achieved without fundamentally redesigning the production line, thus balancing manufacturing ease with performance improvement.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electret webs demonstrate improved charge retention and filtration performance, achieving effective particle capture in aerosol filters with enhanced properties over traditional thermoplastic resin webs, particularly in filtration media applications.

Implementation Method 1

An electret is a dielectric material that exhibits a quasi-permanent electrical charge. Electrets are useful in a variety of devices including, e.g. cling films, air filters, filtering facepieces, and respirators

Methodology Applied
Scientific EffectElectrostatic charge: Electrostatics

Implementation Method 2

Other methods include, for example, charging the fibers after the web is formed, by means of a corona discharge

Methodology Applied
Scientific EffectCorona discharge: Corona Discharge

Implementation Method 3

electrets are effective in enhancing particle capture in aerosol filters

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Data Source

PatentEP4069898B1Thiolate salt melt additives
Publication Date: 2023.06.21 3M INNOVATIVE PROPERTIES CO
  • EP4069898B1 patent drawing
  • EP4069898B1 patent drawing
  • EP4069898B1 patent drawing

AI summary

Charged polymeric webs, such as electret webs, include a thermoplastic resin and a charge-enhancing additive. The additives are a mercapto-benzothiazole salts or mercapto-benzoxazole salts. The electret webs may be a non-woven fibrous web or a film. The electret webs are suitable for use as filter media.