Three-Layer Inter-Electrode Insulating Film for Non-Volatile Memory

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Solution Overview

Problem

Current non-volatile semiconductor memory devices face challenges in minimizing memory cell leakage and threshold voltage shifts due to the diffusion of metals and defects in the inter-electrode insulating films, which affect the storage and retrieval of charges.

Innovation Solution

A non-volatile semiconductor memory device configuration that includes a three-layer inter-electrode insulating film structure with a lower layer, intermediate layer, and upper layer, where the intermediate layer has a higher barrier height and contains a first element with a varying ratio relative to a second element, preventing metal diffusion and reducing defects, and a floating gate electrode with a three-layer structure to manage charge accumulation and leakage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If a high-dielectric film is used as an inter-electrode insulating film to address miniaturization of memory cells, then the memory cell size is reduced, but metal diffusion and defects in the insulating film increase, causing charge leakage and threshold voltage shifts

Engineering Contradiction:
Improvememory cell sizeVSAvoidcharge storage reliability
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The inter-electrode insulating film is divided into three distinct layers: a lower layer insulating film, an intermediate insulating film, and an upper layer insulating film. Each layer has specific compositional characteristics that work together to prevent metal diffusion while maintaining miniaturization benefits.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The lower layer insulating film has a composition that varies through its thickness, with a first element to second element ratio that is larger on the side closer to the intermediate insulating film than on the side closer to the floating gate electrode. This local compositional variation optimizes both diffusion prevention and electrical performance.

Inventive Principle:
Principle #3Local quality

2Productivity

If the inter-electrode insulating film is miniaturized to increase storage density, then more memory cells fit in the same area, but metal diffusion becomes more significant, causing threshold voltage shifts

Engineering Contradiction:
Improvememory storage densityVSAvoidthreshold voltage control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The intermediate insulating film acts as a mediator between the lower and upper layer insulating films, providing an additional barrier against metal diffusion and helping to maintain precise threshold voltage control in miniaturized memory cells.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The inter-electrode insulating film uses a composite structure with three layers having different compositions and properties, combining the benefits of each material to achieve both high storage density and precise voltage control.

Inventive Principle:
Principle #40Composite materials

3Device complexity

If a simple single-layer insulating film is used, then the device structure is simpler and manufacturing is easier, but it cannot effectively prevent metal diffusion and charge leakage

Engineering Contradiction:
Improveinsulating film structureVSAvoidmetal diffusion and charge leakage
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The insulating film is segmented into three functional layers, each targeting specific harmful effects: the lower layer provides the primary diffusion barrier, the intermediate layer enhances protection and provides compositional transition, and the upper layer completes the insulating structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The composition parameters of the insulating film are changed through the three-layer structure, with the lower layer having a specific first element to second element ratio that varies through its thickness, optimizing the balance between diffusion prevention and electrical characteristics.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces charge leakage and shifts in threshold voltage by controlling the diffusion of metals and defects, enhancing the reliability and efficiency of memory cell operations.

Implementation Method 1

The intermediate insulating film contains a first element. The lower layer insulating film contains the first element and a second element, such that a ratio of the first element relative to the second element is larger on a side closer to the intermediate insulating film than on a side closer to the floating gate electrode.

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

The intermediate insulating film contains a first element. The lower layer insulating film contains the first element and a second element, such that a ratio of the first element relative to the second element is larger on a side closer to the intermediate insulating film than on a side closer to the floating gate electrode.

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS9825184B2Non-volatile semiconductor memory device
Publication Date: 2017.11.21 KIOXIA CORP
  • US9825184B2 patent drawing
  • US9825184B2 patent drawing
  • US9825184B2 patent drawing

AI summary

According to one embodiment, an inter-electrode insulating film interposed between a floating gate electrode and a control gate electrode includes a lower layer insulating film disposed on a side closer to the floating gate electrode, an upper layer insulating film disposed on a side closer to the control gate electrode, and an intermediate insulating film interposed between the lower layer insulating film and the upper layer insulating film, wherein the intermediate insulating film contains a first element, and the lower layer insulating film contains the first element and a second element, such that a ratio of the first element relative to the second element is larger on a side closer to the intermediate insulating film than on a side closer to the floating gate electrode.