Three-Piece Can Steel Sheet Nitrogen Alloying

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Solution Overview

Problem

Conventional methods for manufacturing high-strength steel sheets for three-piece cans face challenges in achieving a balance between strength and elongation, leading to issues with processability and roundness, particularly during roll forming and retort sterilization, where the steel sheet's strength is compromised by thinning and work hardening.

Innovation Solution

The solution involves increasing nitrogen content in the steel sheet to enhance strength and elongation, combined with strain aging hardening, which allows for improved roll formability and roundness, and applying a baking process after repair coating to further increase strength, thereby ensuring a yield strength of 440 MPa or more and total elongation of 12% or more.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If the sheet thickness is reduced for cost reduction and weight reduction, then the can weight decreases and environmental protection is improved, but the can strength is reduced

Engineering Contradiction:
Improvecan weightVSAvoidcan strength
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The invention changes the material parameters by precisely controlling the chemical composition (C: 0.005-0.030%, Si: 0.010-0.050%, Mn: 0.50-2.00%, Al: 0.005-0.050%, N: 0.005-0.020%) and applying specific heat treatment parameters (annealing temperature and time) to achieve the required strength with thinner sheets

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite microstructure consisting of ferrite and retained austenite phases through controlled composition and heat treatment, where the ferrite provides ductility and the retained austenite (3-15%) provides strength through TRIP effect, enabling thin sheets to maintain high strength

Inventive Principle:
Principle #40Composite materials

2Strength

If C is added to increase the strength of the steel sheet, then the steel sheet strength increases, but slab cracking occurs due to peritectic reaction

Engineering Contradiction:
Improvesteel sheet strengthVSAvoidslab cracking
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The invention changes the approach from high carbon addition to precise low-carbon control (0.005-0.030%) combined with alloying elements (Si, Mn, Al, N) and heat treatment to achieve strength without triggering peritectic reaction and slab cracking

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces Si and Mn as intermediary elements that contribute to solid solution strengthening and precipitation hardening, allowing the steel to achieve required strength without relying on high carbon content that causes peritectic reaction

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If the second cold rolling is performed for work hardening to increase the steel sheet strength, then the steel sheet strength increases, but the elongation decreases causing cracking during flanging processing

Engineering Contradiction:
Improvesteel sheet strengthVSAvoidprocessability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention changes the strengthening mechanism from work hardening through cold rolling to precipitation hardening through controlled heat treatment, specifically annealing that produces 3-15% retained austenite, which maintains high strength while preserving elongation for flanging operations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention utilizes the phase transition during annealing to form retained austenite from martensite or bainite, which can transform to martensite during deformation (TRIP effect), providing both strength and ductility without the need for aggressive cold rolling

Inventive Principle:
Principle #36Phase transitions

4Strength

If a high strength material is used to keep the can strength, then the can strength is maintained, but the shape fixability is reduced causing the cylindrical shape to not be formed after roll forming

Engineering Contradiction:
Improvecan strengthVSAvoidcylindrical shape
Core Design Contradiction:
StrengthVSShape

Solution Approach 1:

The invention changes the material properties through controlled composition (low C, specific Si, Mn, Al, N ranges) and annealing parameters to achieve a balanced microstructure with 3-15% retained austenite, providing both strength and shape fixability for roll forming

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a steel sheet with excellent processability and roundness, preventing dents during retort sterilization and maintaining can strength under external pressure, while facilitating easier manufacturing and maintaining the cylindrical shape during roll forming.

Implementation Method 1

The steel sheet has a yield strength of 440 MPa or more and a total elongation of 12% or more after strain aging hardening

Methodology Applied
Scientific EffectStrain aging hardening: Precipitation Hardening

Implementation Method 2

the steel sheet is subjected to annealing and then rapidly cooled

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentEP2860124B2Three-piece can and method for producing same
Publication Date: 2020.03.18 JFE STEEL CORP

AI summary

Provided are an especially high-strength three-piece can and a method for manufacturing the three-piece can. A three-piece can includes a can body obtained by forming a steel sheet such that a roundness of the can is 0.34 mm or less. The steel sheet contains: by mass%, C: 0.020% or more and 0.100% or less; Si: 0.10% or less; Mn: 0.10% or more and 0.80% or less; P: 0.001% or more and 0.100% or less; S: 0.001% or more and 0.020% or less; Al: 0.005% or more and 0.100% or less; and N: 0.0130% or more and 0.0200% or less. The balance is Fe and inevitable impurities. The steel sheet has a yield strength of 440 MPa or more and a total elongation of 12% or more.