Through-Glass Via Electrode Surface Texture for Thermal Shock Reliability

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Solution Overview

Problem

Existing multilayer wiring substrates with through glass vias (TGVs) face issues with thermal shock resistance and connectivity between conductive layers, leading to potential cracking and reliability concerns, particularly when using glass substrates thinner than 300 μm.

Innovation Solution

A multilayer wiring substrate with a glass substrate featuring a through electrode having a bottom surface with unevenness of ±0.5 μm to 5 μm in height, where a hydrofluoric acid resistant metal layer and seed layers are formed on the uneven surface, followed by electrolytic plating to enhance connectivity and thermal shock resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a through glass via is formed to a glass substrate, then connectivity between conductive layers is achieved, but the mechanical strength of the glass substrate deteriorates and glass cracking may occur

Engineering Contradiction:
Improveconnectivity of through electrodeVSAvoidmechanical strength of glass substrate
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

A modified part is formed in the glass substrate at the via position before etching the through glass via. This preliminary modification creates a localized region with altered physical properties that prevents crack propagation during subsequent processing and thermal cycling, thereby maintaining mechanical strength while enabling connectivity.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The modified part acts as a cushioning region that absorbs and distributes stress concentrations around the via hole. By pre-forming this modified zone, the structure is prepared to withstand thermal expansion differences and mechanical stresses that would otherwise cause cracking in thin glass substrates.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

2Length of moving object

If the thickness of glass is reduced to 300 μm or less, then the substrate becomes more suitable for certain applications, but glass cracking occurs during conveyance and processing

Engineering Contradiction:
Improvethickness of glass substrateVSAvoidresistance to glass cracking
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The modified part is formed before any subsequent processing steps. This pre-modification creates a stress-distributing zone that compensates for the reduced mechanical strength inherent in thinner glass substrates, preventing cracking during conveyance and processing despite the reduced thickness.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The modification is applied locally at the via position rather than throughout the entire substrate. This localized modification strengthens the critical region around the via hole without requiring overall thickening of the substrate, thus maintaining the thin profile while improving crack resistance.

Inventive Principle:
Principle #3Local quality

3Ease of operation

If laser treatment is performed before forming conductive parts, then handling of substrate is facilitated and conductive parts are protected from processing heat, but additional process steps are required

Engineering Contradiction:
Improvehandling of substrateVSAvoidnumber of process steps
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The laser treatment that forms the modified part is combined with the via formation process. The same laser system and processing sequence accomplish both the modification for crack prevention and the preparation for via etching, eliminating the need for separate modification and via formation steps.

Inventive Principle:
Principle #5Merging (Combining)

4Ease of manufacture

If conventional through glass via formation is used, then manufacturing simplicity is maintained, but thermal shock resistance of through electrode is insufficient

Engineering Contradiction:
Improvesimplicity of via formationVSAvoidthermal shock resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The modified part is formed in advance before via etching and conductive material deposition. This preliminary step creates a stress-absorbing zone that prevents cracking during thermal cycling, improving thermal shock resistance without adding complex equipment or significantly complicating the manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach significantly improves the thermal shock resistance and reliability of the through electrode by increasing the contact area and preventing disconnections during thermal cycles, while reducing via filling failures and air bubble issues during plating.

Implementation Method 1

irradiating a glass substrate having a first surface and a second surface with a laser to form a modified part reaching the first surface in the glass substrate and form, on the first surface of the glass substrate, an unevenness

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

etching the modified part from the second surface of the glass substrate using an etching liquid to form a through glass via

Methodology Applied
Scientific EffectChemical etching:

Implementation Method 3

energizing the second seed layer to perform an electrolytic plating treatment

Methodology Applied
Scientific EffectElectrolytic plating: Electrolysis

Data Source

PatentUS20240349427A1Multilayer wiring substrate and method of manufacturing the multilayer wiring substrate
Publication Date: 2024.10.17 TOPPAN HOLDINGS INC
  • US20240349427A1 patent drawing
  • US20240349427A1 patent drawing
  • US20240349427A1 patent drawing

AI summary

A multilayer wiring substrate including a glass substrate provided with a through electrode, in which a bottom surface part of the through electrode provided to the glass substrate contains an unevenness in which an absolute value of a height difference from a first surface of the glass substrate is ±0.5 μm or more and 5 μm or less. For manufacturing this, a glass substrate is irradiated with a laser, a modified part reaching a first surface is formed in the glass substrate, and an unevenness is formed on the first surface of the glass substrate. Then, a hydrofluoric acid resistant metal layer and/or a first seed layer on each of which a shape of the unevenness is transferred is formed. Thereafter, a through glass via is formed by hydrofluoric acid, and then a second seed layer on which the uneven shape is transferred is formed in the through glass via.