Through-Via Residue Oxidation for Reliable 3D Semiconductor Interconnects

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Solution Overview

Problem

Conventional semiconductor package technologies face challenges such as signal loss, high power consumption, and design constraints due to two-dimensional interconnection methods, while three-dimensional integrated circuit (3D-IC) package technologies using through-silicon vias (TSVs) aim to address these issues but struggle with etch residue removal affecting electric reliability.

Innovation Solution

The method involves forming a semiconductor device with a metal pattern and a second structure, where a via hole is etched to expose the metal pattern, and the etch residue is oxidized and removed in-situ within a single process chamber, creating a recessed surface with varying roughness to enhance adhesion and reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional two-dimensional wire-bonding interconnection is used, then device design flexibility is maintained, but signal loss and power consumption increase

Engineering Contradiction:
Improvepower consumptionVSAvoidinterconnection structure
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent transitions from conventional two-dimensional wire-bonding interconnection to three-dimensional through-silicon via (TSV) interconnection. The TSV structure extends vertically through the substrate, enabling direct vertical connections between stacked semiconductor chips, thereby reducing wiring lengths and power consumption while maintaining design flexibility

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If TSV-based 3D-IC package technology is used, then wiring lengths are reduced and IC placement density increases, but etch residue removal becomes difficult affecting reliability

Engineering Contradiction:
Improveelectric reliabilityVSAvoidetch residue removal
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent performs preliminary oxidation of etch residues immediately after the via etching process, converting organic etch residues into inorganic oxide compounds before subsequent cleaning steps. This preliminary action makes the residues more susceptible to removal and prevents contamination of the TSV structure

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces an oxidation process as an intermediary step between etching and cleaning. This oxidation process transforms the etch residues into a different chemical form (oxide) that can be more effectively removed by subsequent cleaning processes, thereby improving the ease of manufacture

Inventive Principle:
Principle #24Intermediary (Mediator)

3Loss of energy

If TSV-based 3D-IC package technology is used, then signal loss is reduced, but manufacturing process complexity increases

Engineering Contradiction:
Improvesignal lossVSAvoidmanufacturing process
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent combines the oxidation process with the existing via etching process by performing oxidation in the same process chamber immediately after etching. This merging of processes reduces the number of separate steps and equipment transitions, thereby managing manufacturing process complexity while achieving the benefit of reduced signal loss through improved via cleanliness

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively removes etch residues, improving the adhesion strength between the through via and peripheral structures, thereby enhancing the electric reliability of semiconductor devices.

Implementation Method 1

oxidizing a first etch residue in the via hole to convert the first etch residue into an oxidized first etch residue

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

reducing the metal oxide, before or after removing the oxidized first etch residue

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS11791211B2Semiconductor devices including through vias and methods of fabricating the same
Publication Date: 2023.10.17 SAMSUNG ELECTRONICS CO LTD
  • US11791211B2 patent drawing
  • US11791211B2 patent drawing
  • US11791211B2 patent drawing

AI summary

Disclosed are semiconductor devices including through vias and methods of fabricating the same. The methods may include forming a first structure including a metal pattern and a second structure on the first structure. The metal pattern includes an upper surface facing the second structure. The methods may also include etching the second structure to form a via hole exposing the metal pattern, oxidizing a first etch residue in the via hole to convert the first etch residue into an oxidized first etch residue, and removing the oxidized first etch residue. After removing the oxidized first etch residue, the upper surface of the metal pattern may include a first portion that includes a recess and has a first surface roughness and a second portion that is different from the first portion and has a second surface roughness. The first surface roughness may be greater than the second surface roughness.