TiAlCN Coating Composition for Chipping-Resistant Cutting Tools

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Solution Overview

Problem

Existing coated tools with Ti-Al-based complex nitride layers exhibit insufficient chipping and wear resistance during high-speed intermittent cutting of alloy steel, especially under high-temperature and impact load conditions, leading to abnormal wear such as chipping.

Innovation Solution

A surface-coated cutting tool with a TiAlCN layer having a NaCl type face-centered cubic structure, where the lattice strain is optimized by controlling the plane spacing differences and incorporating a small amount of Cl, resulting in improved hardness and wear resistance through a specific chemical vapor deposition process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a Ti-Al-based layer of complex nitride is used as a hard coating layer, then wear resistance is improved, but chipping resistance deteriorates under high-speed intermittent cutting conditions

Engineering Contradiction:
Improvewear resistanceVSAvoidchipping resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the aluminum content (0.60 ≤ Xavg ≤ 0.95) and carbon content (0 ≤ Yavg ≤ 0.005) in the TiAlCN layer, and by controlling the lattice strain through the relationship between d(111) and d(200) plane spacings. These parameter optimizations simultaneously improve both wear resistance and chipping resistance, resolving the technical contradiction between hardness and toughness in the coating layer.

Inventive Principle:
Principle #35Parameter changes

2Temperature

If the hard coating layer is optimized for wear resistance, then cutting edge durability under high temperature is improved, but impact load resistance deteriorates

Engineering Contradiction:
Improvehigh-temperature heat resistanceVSAvoidimpact load resistance
Core Design Contradiction:
TemperatureVSForce

Solution Approach 1:

The patent optimizes the coating composition parameters (Al content Xavg, C content Yavg, and Cl content Z) and crystal structure parameters (lattice plane spacings d(111) and d(200)) to achieve a balance between heat resistance and impact resistance. The controlled lattice strain and faceted structure enable the coating to withstand both thermal and mechanical stresses simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized TiAlCN layer provides excellent chipping and wear resistance, extending tool life during high-speed intermittent cutting of alloy steel by enhancing both hardness and toughness, preventing chipping and fracture.

Implementation Method 1

formed by a chemical vapor deposition method

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

measured by using an X-ray diffraction device

Methodology Applied
Scientific EffectX-ray diffraction: X-Ray

Data Source

PatentEP3572172B1Surface coated cutting tool having hard coating layer exhibiting excellent chipping resistance and wear resistance
Publication Date: 2022.06.22 MITSUBISHI MATERIALS CORP
  • EP3572172B1 patent drawing
  • EP3572172B1 patent drawing
  • EP3572172B1 patent drawing

AI summary

A surface-coated cutting tool including at least a TiAlCN layer, in which the layer is expressed by a composition formula: (Ti1-XAlX)(CYN1-Y), an average content ratio X of Al and an average content ratio Y of C (here, X and Y are atomic ratios) satisfy 0.60 ≤ X ≤ 0.95 and 0 ≤ Y ≤ 0.005, respectively, an average content ratio Z of Cl in the total amount of atoms configuring the TiAlCN phase (here, Z is an atomic ratio) satisfies 0.0001 ≤ Z ≤ 0.004, plane spacings d(111) and d(200) are respectively calculated from X-ray diffraction spectra of (111) plane and (200) plane of crystal grains having a NaCl type face-centered cubic structure in the TiAlCN layer measured by using an X-ray diffraction device, and an absolute value ΔA = |A(111) - A(200)| defined as A(111) = 31/2d(111) and A(200) = 2d(200) satisfies 0.007 Å ≤ ΔA ≤ 0.05.