TiB2-Precipitated Steel Sheet for High-Modulus Formability

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Solution Overview

Problem

Current methods for producing steel sheets with high elasticity modulus and low density face challenges such as residual porosities, chemical composition control issues, and limited formability due to the incorporation of ceramic particles, which are difficult to disperse homogeneously and can lead to surface defects and reduced ductility.

Innovation Solution

A steel composition with specific ranges of C, Ti, B, and other elements is used, along with controlled solidification rates to produce steel sheets with a high volume fraction of fine TiB2 precipitates, ensuring a ferritic structure and improved formability and ductility, while avoiding coarse precipitates that can cause damage during processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If ceramic particles are incorporated into steel to increase elasticity modulus, then the elasticity modulus increases, but the elongation properties decrease and residual porosities remain

Engineering Contradiction:
Improveelasticity modulusVSAvoidelongation properties
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters by precisely controlling C (0.010-0.080%), Ti (3.2-7.5%), and B ((0.45×Ti)-1.35 to (0.45×Ti)-0.43) content to optimize precipitate formation. This compositional parameter optimization allows achieving high elasticity modulus through fine TiB2 precipitates while maintaining adequate elongation properties by preventing coarse precipitate formation that would harm ductility.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of ferrite matrix with finely dispersed TiB2 precipitates. This composite structure at the micro-scale provides both the high elasticity modulus from the ceramic precipitates and the good elongation properties from the ferritic matrix, resolving the contradiction between strength and ductility.

Inventive Principle:
Principle #40Composite materials

2Strength

If powder metallurgy process is used to manufacture steel with ceramic particles, then elasticity modulus increases, but residual porosities remain and manufacturing costs increase

Engineering Contradiction:
Improveelasticity modulusVSAvoidmanufacturing process complexity
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent extracts the ceramic particle incorporation step from the complex powder metallurgy process. Instead of adding ceramic powders separately through extrinsic addition, the TiB2 precipitates form in-situ during steel solidification through controlled chemical composition, eliminating the need for separate powder blending, compacting, and sintering operations.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The steel composition is designed to self-form TiB2 precipitates during normal solidification and cooling processes. The controlled C, Ti, and B contents enable automatic precipitate formation without requiring external intervention or specialized manufacturing steps, making the process suitable for mass production.

Inventive Principle:
Principle #25Self-service

3Strength

If large quantity of ceramic particles are added, then elasticity modulus increases, but elongation properties decrease and surface defects occur

Engineering Contradiction:
Improveelasticity modulusVSAvoidsurface quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating fine TiB2 precipitates distributed throughout the steel matrix rather than large particles. The controlled composition ensures precipitates form at the appropriate scale (fine dispersion) rather than coarse aggregation, providing local reinforcement without creating surface defects or harming elongation properties.

Inventive Principle:
Principle #3Local quality

4Productivity

If conventional casting process is used, then production efficiency is high, but homogeneous particle dispersion is difficult and particles agglomerate

Engineering Contradiction:
Improvemass production capabilityVSAvoidparticle distribution homogeneity
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The steel composition is formulated to self-disperse TiB2 precipitates homogeneously during solidification. The controlled C, Ti, and B contents ensure uniform precipitate formation throughout the molten steel, eliminating agglomeration issues while maintaining high production efficiency through conventional casting processes.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in steel sheets with enhanced specific elasticity modulus, high formability, and toughness, allowing for the production of parts with complex shapes without surface defects or internal damage, suitable for automotive industry requirements.

Implementation Method 1

TiB2, Fe2B and/or TiC precipitates form upon casting

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

the steel being solidified during the casting with a solidification rate comprised between 0.03 cm/s and 5 cm/s

Methodology Applied
Scientific EffectSolidification: Freezing

Data Source

PatentUS11427898B2High formability steel sheet for the manufacture of lightweight structural parts and manufacturing process
Publication Date: 2022.08.30 ARCELORMITTAL SA
  • US11427898B2 patent drawing
  • US11427898B2 patent drawing
  • US11427898B2 patent drawing

AI summary

A steel sheet has a composition comprising, by weight: 0.010%≤C≤0.080%, 0.06%≤Mn≤3%, Si≤1.5%, 0.005%≤Al≤1.5%, S≤0.030%, P≤0.040%, Ti and B such that: 3.2%≤Ti≤7.5% and (0.45×Ti)−1.35≤B≤(0.45×Ti)−0.43, optionally Ni≤1%, Mo≤1%, Cr≤3%, Nb≤0.1%, V≤0.1%, the remainder being iron and unavoidable impurities resulting from the smelting. The steel sheet has a structure consisting of ferrite, at most 10% of austenite, and precipitates comprising eutectic precipitates of TiB2, the volume fraction of TiB2 precipitates with respect to the whole structure being of at least 9%, the proportion of TiB2 precipitates having a surface area lower than 8 μm2 being of at least 96%.