TiC-Zr-Si Composite Particles Oxidation Resistance

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Solution Overview

Problem

Existing carbide fine particles lack excellent oxidation resistance, which limits their range of applications and additional functional requirements.

Innovation Solution

Composite particles are produced by combining TiC with at least one of Zr and Si, using a gas-phase process such as thermal plasma, with preferred mass content ranges of 0.1 to 20% for Zr and Si individually, or 0.1 to 10% each when combined.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional carbide fine particles are used, then production is simple and cost-effective, but oxidation resistance is poor

Engineering Contradiction:
Improveoxidation resistanceVSAvoidparticle composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining TiC with Zr and/or Si to create composite particles with enhanced oxidation resistance. The composite structure allows the base TiC to maintain its functional properties while the added elements provide oxidation protection, directly resolving the contradiction between simple composition and oxidation resistance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If TiC is combined with Zr and Si, then oxidation resistance is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improveoxidation resistanceVSAvoidcontent control precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent specifies precise parameter ranges (Zr: 0.1-20 mass%, Si: 0.1-20 mass%, with combined content each 0.1-10 mass%) to optimize oxidation resistance while managing manufacturing complexity. By defining these specific parameter windows, the invention balances performance improvement with practical manufacturability, addressing the contradiction between oxidation resistance and manufacturing precision requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting composite particles exhibit excellent oxidation resistance, maintaining their properties and functionality even after baking at elevated temperatures, thus expanding their application potential.

Implementation Method 1

a step of converting a slurry, in which the feedstock is dispersed in a liquid, into droplets and supplying the droplets into a thermal plasma flame

Methodology Applied
Scientific EffectThermal plasma: Plasma

Implementation Method 2

the thermal plasma flame; and a step of supplying cooling gas to a terminating portion of the thermal plasma flame to thereby produce the composite particles

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

a step of supplying cooling gas to a terminating portion of the thermal plasma flame to thereby produce the composite particles

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS12291487B2Composite particles
Publication Date: 2025.05.06 NISSHIN ENG
  • US12291487B2 patent drawing
  • US12291487B2 patent drawing
  • US12291487B2 patent drawing

AI summary

Provided are: composite particles having excellent oxidation resistance; and a method for producing composite particles. The composite particles are obtained by forming a composite of TiC and at least one of Zr and Si. In the method for producing composite particles, a titanium oxide powder and at least one of a zirconium oxide powder and a silicon oxide powder are used as raw material powders, and composite particles are produced using a gas phase method.