Tilted Cholesteric Optical Film for Oblique Shade Reduction

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Solution Overview

Problem

Liquid crystal display devices with immobilized cholesteric liquid crystalline phases experience shade unevenness when viewed from oblique directions due to non-zero oblique retardation, which existing solutions fail to fundamentally address by using additional compensation layers rather than modifying the cholesteric layer itself.

Innovation Solution

An optical film with a light reflection layer where liquid crystal molecules are immobilized, forming a helical structure with a tilt angle of 15° to 55°, specifically 25° to 45°, is developed, using a polymerizable liquid crystal composition that includes a chiral agent, and is manufactured by curing between supports with alignment films, reducing oblique retardation and enhancing front surface brightness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a cholesteric liquid crystalline phase is used as a light reflection layer, then circular polarization reflecting properties are achieved, but shade unevenness occurs when viewed from oblique directions due to non-zero oblique retardation

Engineering Contradiction:
Improvecircular polarization reflecting propertiesVSAvoidshade unevenness
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the fundamental optical parameter of the light reflection layer by using a tilted liquid crystal phase (SmC* or tilted cholesteric phase) instead of a conventional cholesteric phase. This parameter change in the molecular orientation (tilt angle of 15° to 55° relative to the substrate normal) fundamentally reduces the oblique retardation, thereby suppressing shade unevenness while maintaining circular polarization reflecting properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs a composite light reflection layer comprising liquid crystal molecules with specific chiral dopants and tilt-inducing agents. This composite material structure achieves both the desired tilt angle and the circular polarization reflection properties, resolving the contradiction between maintaining reflection functionality and eliminating shade unevenness

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If a conventional cholesteric liquid crystalline phase with zero in-plane retardation is used, then polarized light recycling is achieved, but oblique retardation causes shade change when seen from oblique direction

Engineering Contradiction:
Improvelight utilization rateVSAvoidoblique retardation
Core Design Contradiction:
Loss of energyVSObject-affected harmful factors

Solution Approach 1:

The invention fundamentally changes the retardation parameter by transitioning from a conventional cholesteric phase (with zero in-plane but non-zero oblique retardation) to a tilted liquid crystal phase. This parameter transformation achieves both low oblique retardation and effective polarized light recycling, as the tilted molecular structure allows simultaneous optimization of both optical properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optical film achieves a significant reduction in oblique retardation, thereby suppressing shade changes when viewed from oblique directions, resulting in improved front surface brightness and reduced oblique shade variations in liquid crystal display devices.

Implementation Method 1

a liquid crystal molecule forms a helical structure in a film thickness direction of the light reflection layer

Methodology Applied
Scientific EffectHelical structure formation: Cholesteric Liquid Crystal

Implementation Method 2

alignment of liquid crystal molecules is immobilized

Methodology Applied
Scientific EffectLiquid crystal alignment: Liquid Crystals

Implementation Method 3

using a polymerizable liquid crystal composition that includes a chiral agent, and is manufactured by curing between supports with alignment films

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS10495791B2Optical film, liquid crystal display device, and manufacturing method of optical film
Publication Date: 2019.12.03 FUJIFILM CORP
  • US10495791B2 patent drawing
  • US10495791B2 patent drawing
  • US10495791B2 patent drawing

AI summary

The present invention provides an optical film including a light reflection layer, in which the light reflection layer is a layer in which alignment of liquid crystal molecules is immobilized, the liquid crystal molecule forms a helical structure in a film thickness direction of the light reflection layer, and a tilt angle of the liquid crystal molecule is 15° to 55°. The present invention also provides a manufacturing method of the optical film including curing a polymerizable liquid crystal composition including a liquid crystal compound and a chiral agent interposed between a support and another support. In the optical film according to the present invention, an absolute value of oblique retardation is smaller. In the liquid crystal display device including the optical film, front surface brightness is high and an oblique change in the shade is suppressed.