Tin Compound Apparatus Cleaning to Prevent Stanoxane Contamination

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Solution Overview

Problem

Tin compounds react with oxygen and water to form stanoxane compounds, which adhere to and remain on apparatuses, leading to impurities and decreased purity in subsequent synthesis or storage.

Innovation Solution

A method involving steps of cleaning an apparatus with a non-polar solvent, followed by alcohol, and then ultrapure water with a resistivity of 17 MΩ·cm, optionally including an acidic aqueous solution, to effectively remove impurities and maintain high purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If tin compound is stored or processed in apparatus, then tin compound can be handled and processed, but stanoxane compounds form and adhere to apparatus surfaces causing impurity contamination

Engineering Contradiction:
Improvepurity of tin compoundVSAvoidstanoxane compound formation and adhesion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary action by performing cleaning with non-polar solvent, alcohol, and ultrapure water in sequence before the apparatus is used for storing or processing tin compounds. This preliminary cleaning removes potential contaminants and prevents stanoxane compound adhesion from occurring in the first place, thereby maintaining tin compound purity without requiring intervention after contamination occurs.

Inventive Principle:
Principle #10Preliminary action

2Ease of manufacture

If conventional cleaning methods are used, then apparatus can be cleaned, but impurities remain and tin compound purity decreases

Engineering Contradiction:
Improvecleaning process simplicityVSAvoidpurity of tin compound
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent segments the cleaning process into three distinct sequential steps: (A) cleaning with non-polar solvent to remove organic contaminants, (B) cleaning with alcohol to remove intermediate contaminants, and (C) cleaning with ultrapure water to remove inorganic contaminants and residual cleaning agents. This segmentation allows each step to target specific types of impurities, achieving high purity results while maintaining a relatively simple overall process.

Inventive Principle:
Principle #1Segmentation

3Quantity of substance

If tin compound reacts with oxygen and water, then stanoxane compounds are formed, but these compounds adhere to apparatus and contaminate subsequent tin compound batches

Engineering Contradiction:
Improveamount of tin compound processedVSAvoidtin compound purity
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The patent converts the harmful reaction between tin compound, oxygen, and water that produces adhering stanoxane compounds into a beneficial cleaning opportunity. By deliberately introducing controlled amounts of oxygen and water through the structured cleaning sequence (non-polar solvent → alcohol → ultrapure water), the apparatus surfaces are cleaned of previous stanoxane deposits, and the final ultrapure water rinse prevents new stanoxane formation by leaving no organic residues that could catalyze the reaction.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method efficiently and safely cleans the apparatus, suppressing impurity formation, ensuring high purity and preventing purity loss of tin compounds during storage or reuse.

Implementation Method 1

a step of cleaning the apparatus with a non-polar solvent

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

cleaning the apparatus with a non-polar solvent

Methodology Applied
Scientific EffectDesorption: Desorption

Implementation Method 3

a step of cleaning with an alcohol

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 4

a step of cleaning with an alcohol

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 5

a step of cleaning the apparatus with ultrapure water with a resistivity of 17 MΩ·cm at 25° C.

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 6

a step of cleaning the apparatus with ultrapure water with a resistivity of 17 MΩ·cm at 25° C.

Methodology Applied
Scientific EffectRinsing:

Implementation Method 7

a step of cleaning with an acidic aqueous solution following the step of cleaning with an alcohol

Methodology Applied
Scientific EffectChemical reaction: Reaction (physics)

Implementation Method 8

a step of cleaning with an acidic aqueous solution

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS20250222496A1Method for cleaning an apparatus for a tin compound and the cleaned apparatus obtained thereby
Publication Date: 2025.07.10 MITSUBISHI CHEM CORP

AI summary

A method for efficiently and safely cleaning an apparatus for tin compound and a highly purified tin compound apparatus are provided. A cleaning method for an apparatus that has been in contact with a tin compound having formula (1) below includes at least steps (A) to (C), in which step (B) is performed after step (A), and step (C) is performed after step (B):(A) a step of cleaning the apparatus with a non-protic solvent,(B) a step of cleaning the apparatus with alcohol, and(C) a step of cleaning the apparatus with ultrapure water having a resistivity value of 17 MΩ·cm at 25° C.RpSnXm  (1)In formula (1), R is a hydrocarbon group, p is an integer from 1 to 3, X is a hydrolyzable substituent, and m=4−p.