Tin Fluoride-Carbon Composite Anode for Sodium Batteries
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Solution Overview
Problem
Current anode materials for sodium secondary batteries face challenges in achieving high charge/discharge capacity, cycle life, and rate performance, limiting their application in energy storage systems.
Innovation Solution
A tin fluoride-carbon composite anode material is developed, comprising tin fluoride and a carbonaceous material, where the tin fluoride is mixed with carbon under an inert atmosphere to form a composite with improved electrical conductivity and reduced particle size, enhancing electrochemical performance.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If conventional anode materials (silicon and graphite) are used in sodium secondary batteries, then manufacturing simplicity is maintained, but charge/discharge capacity and cycle life are insufficient
Solution Approach 1:
The patent employs a composite anode material consisting of tin fluoride particles dispersed in a carbonaceous matrix. This composite structure combines the high capacity of tin fluoride with the stability and conductivity of carbon, resolving the contradiction between achieving high cycle life and maintaining manufacturing simplicity. The carbonaceous material serves as both a structural framework and a conductive network, enabling straightforward manufacturing while delivering superior electrochemical performance.
Solution Approach 2:
The patent applies local quality by creating a heterogeneous structure where tin fluoride particles are distributed within the carbonaceous matrix. Different regions of the anode material serve different functions: tin fluoride provides high capacity sites for sodium ion insertion, while the carbon matrix provides structural integrity and electrical conductivity. This localized functional distribution achieves high reliability without complicating the overall manufacturing process.
2Productivity
If tin fluoride is used as anode material, then charge/discharge capacity is improved, but electrical conductivity is insufficient
Solution Approach 1:
The patent creates a composite material where tin fluoride particles are embedded in a carbonaceous matrix. The carbon component provides excellent electrical conductivity and structural stability, while tin fluoride contributes high charge/discharge capacity through reversible sodium ion insertion. This composite approach resolves the contradiction by combining materials with complementary properties.
Solution Approach 2:
The carbonaceous material acts as an intermediary between tin fluoride particles and the electrolyte, facilitating electron transport and maintaining electrical conductivity. The carbon matrix serves as a conductive network that connects tin fluoride particles to the current collector, enabling efficient charge transfer while allowing tin fluoride to maintain its high capacity characteristics.
3Productivity
If anode materials are optimized for high capacity, then charge/discharge capacity is improved, but rate performance deteriorates
Solution Approach 1:
The patent creates a hierarchical structure where tin fluoride particles of optimized size are distributed within the carbon matrix. This local optimization ensures that high-capacity regions (tin fluoride) are surrounded by high-conductivity regions (carbon), enabling fast electron and ion transport. The local quality approach allows the material to deliver high capacity at various rates by maintaining efficient transport pathways throughout the structure.
Solution Approach 2:
The composite structure combines tin fluoride's high capacity with carbon's superior rate performance. The carbon matrix provides rapid electron transport pathways and maintains structural integrity during fast charging/discharging cycles, while tin fluoride particles provide the high capacity mechanism. This synergistic combination resolves the contradiction between capacity and rate performance.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The tin fluoride-carbon composite anode material exhibits high charge/discharge capacity, excellent cycle life, and high rate performance, outperforming traditional anode materials in sodium secondary batteries.
Implementation Method 1
mixing a tin fluoride with a carbonaceous material under an inert atmosphere
Implementation Method 2
anode material for a secondary battery that can be used to improve the electrochemical performance
Data Source
AI summary
Disclosed is an anode material for a sodium secondary battery. The anode material includes a tin fluoride-carbon composite composed of a tin fluoride and a carbonaceous material. The anode material can be used to improve the charge/discharge capacity, charge/discharge efficiency, and electrochemical activity of a sodium secondary battery. Also provided are a method for preparing the anode material and a sodium secondary battery including the anode material.


