Tinting Base for Facade Paints Preventing Snail Trails

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Solution Overview

Problem

Polymer-bound facade paints, especially those in dark or intense colors, tend to form glossy streaks known as 'snail trails' due to the leaching of surface-active substances, which affect the appearance and quality of the coating, and existing solutions have not completely resolved this issue without compromising storage stability or other properties.

Innovation Solution

The solution involves reducing the content of critical surface-active substances, eliminating phosphates, optimizing wetting agent composition with polyacrylate wetting agents, and using silicone oil to reduce water absorption and prevent leaching, thereby minimizing the formation of snail trails.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If the content of surface-active substances is reduced to minimize snail trail formation, then the appearance quality improves, but storage stability and other coating properties deteriorate

Engineering Contradiction:
Improvesnail trail formationVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical parameters of surface-active substances by replacing conventional surfactants with specific polyacrylate-based wetting agents and phosphoric acid esters. This parameter change allows achieving low snail trail formation (improved appearance) while maintaining adequate storage stability (improved reliability) through the selected chemical composition ranges.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite approach by combining multiple substances with complementary functions: polyacrylate wetting agents for surface activity, phosphoric acid esters for stability, and silicone oils for water repellency. This composite material system resolves the contradiction by distributing functions across multiple components, allowing reduced overall surfactant content while maintaining performance.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If phosphates are eliminated to reduce snail trails, then appearance quality improves, but wetting and dispersing performance may deteriorate

Engineering Contradiction:
Improvesnail trail formationVSAvoidwetting and dispersing performance
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent extracts and eliminates phosphates from the formulation to prevent snail trail formation. The harmful phosphatic surfactants are completely removed while their beneficial wetting and dispersing functions are replaced by alternative substances (polyacrylate wetting agents and phosphoric acid esters), thus achieving phosphate elimination without performance loss.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces polyacrylate wetting agents and phosphoric acid esters as intermediary substances that mediate between the requirement for wetting/dispersing performance and the need to eliminate phosphates. These intermediaries provide the necessary surface activity without the snail trail-forming properties of conventional phosphatic surfactants.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Duration of action of stationary object

If water absorption is reduced to prevent leaching, then durability improves, but the coating may become less compatible with pigment pastes

Engineering Contradiction:
ImprovedurabilityVSAvoidcompatibility with pigment pastes
Core Design Contradiction:
Duration of action of stationary objectVSAdaptability or versatility

Solution Approach 1:

The patent changes the water absorption parameter by incorporating silicone oils (0.1-2.0 wt.%) that reduce water uptake of the coating film. This parameter change improves durability by preventing leaching while the selected silicone oil types and concentrations are optimized to maintain compatibility with existing pigment pastes, thus avoiding adverse effects on adaptability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces or eliminates snail trail formation and improves water resistance, allowing for the production of facade paints with enhanced durability and appearance, even when using existing pigment pastes.

Implementation Method 1

The water-dispersed or dispersible polymer is based on i) acrylic acid esters and vinyl aromatics, in particular styrene, or on ii) acrylic acid esters and vinyl esters of at least one sodium acid (tertiary saturated monocarboxylic acid), in particular versatate

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 2

Polymer-bound coatings are often used on the surface of outdoor structures, such as buildings, where they are more exposed to weathering and other influences

Methodology Applied
Scientific EffectPolymer bonding: Binder

Implementation Method 3

These streaks are caused by the leaching of water-soluble substances such as emulsifiers, wetting/dispersing agents, surfactants, and similar surface-active substances from the coating film

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentEP4242273A1Tinting base for coating materials
Publication Date: 2023.09.13 STO SE & CO KGAA
  • EP4242273A1 patent drawing
  • EP4242273A1 patent drawing
  • EP4242273A1 patent drawing

AI summary

Tinting base for the production of facade paints, comprising at least one organic binder, at least one wetting and dispersing agent, essentially without the addition of pyrophosphates or polyphosphates, in particular tetrapotassium pyrophosphate or sodium polyphosphates; at least one silicone oil; optionally at least one filler and other additives, water to adjust the consistency.