TiO2 Nanoparticle Textile Coating for Self-Disinfecting PPE

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Solution Overview

Problem

Current personal protective equipment (PPE) in the healthcare industry, such as masks and lab coats, can harbor airborne infectious agents, posing a risk of disease transmission due to the difficulty in continuous disinfection and replacement, especially with the prevalence of antimicrobial-resistant pathogens like MRSA.

Innovation Solution

A method involving the impregnation of textiles with titanium dioxide (TiO2) nanoparticles, where the textile is treated with an inorganic base, rinsed, and then contacted with a solution of TiO2 nanoparticles, alcohol, and acid, followed by UV irradiation to create an antimicrobial coating, enhancing the fabric's ability to inhibit microbial growth.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If PPE is continuously changed or disinfected, then antimicrobial protection is improved, but operational complexity and time consumption increase

Engineering Contradiction:
Improveantimicrobial protectionVSAvoidoperational complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The textile is pre-treated with inorganic base and impregnated with TiO2 nanoparticles before final use, so that the antimicrobial coating is already in place and activated. This preliminary preparation eliminates the need for continuous disinfection during operation, as the fabric maintains its antimicrobial properties throughout its service life

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the chemical state of the textile surface by treating it with inorganic base to create reactive sites, then impregnating with TiO2 nanoparticles. The subsequent UV irradiation activates the photocatalytic properties of TiO2, transforming the fabric from a passive barrier to an active antimicrobial agent that continuously neutralizes pathogens

Inventive Principle:
Principle #35Parameter changes

2Reliability

If PPE is continuously disinfected, then antimicrobial activity is maintained, but time and operational efficiency deteriorate

Engineering Contradiction:
Improveantimicrobial activityVSAvoidtime consumption
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The TiO2-coated textile performs self-disinfection through photocatalytic activity when exposed to UV light. The nanoparticles generate reactive oxygen species that continuously destroy microorganisms on the fabric surface without requiring external intervention, making the PPE self-maintaining throughout its use

Inventive Principle:
Principle #25Self-service

3Reliability

If TiO2 nanoparticles are impregnated into textile, then antimicrobial effectiveness is improved, but manufacturing process complexity increases

Engineering Contradiction:
Improveantimicrobial effectivenessVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses chemical parameter changes to simplify the impregnation process. By treating the textile with inorganic base first, the fabric surface gains reactive sites that strongly bind TiO2 nanoparticles. The subsequent use of acid and alcohol solutions adjusts the chemical environment to optimize nanoparticle attachment, creating a durable coating through chemical bonding rather than mechanical adhesion

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining textile fibers with TiO2 nanoparticles. The inorganic base treatment modifies the textile surface to be chemically compatible with TiO2, forming a stable composite structure where the nanoparticles are firmly attached to the fabric matrix, enhancing both durability and antimicrobial effectiveness

Inventive Principle:
Principle #40Composite materials

4Productivity

If same PPE is reused near multiple patients, then resource efficiency is improved, but disease transmission risk increases

Engineering Contradiction:
Improveresource efficiencyVSAvoiddisease transmission risk
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent converts potentially harmful microbial contamination on reused PPE into a beneficial outcome through photocatalytic destruction. When the TiO2-coated fabric is exposed to UV light between uses, any accumulated pathogens are destroyed by reactive oxygen species generated at the nanoparticle surface, transforming the risk of cross-contamination into active pathogen neutralization

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The treated textiles exhibit significantly increased antimicrobial activity, with the ability to inhibit microbial growth by 100 to 1,000 times more effectively than untreated textiles, providing a durable and effective antimicrobial barrier against bacterial and fungal pathogens.

Implementation Method 1

The antimicrobial features of titanium dioxide (TiO2) nanoparticles have previously been assessed. The use of inorganic TiO2 nanoparticles has advanced rapidly due to the amount of work done towards the synthesis and modification of these particles for biomedical applications.

Methodology Applied
Scientific EffectPhotocatalysis: Catalysis

Implementation Method 2

irradiating the coated textile with a UV light to form an antimicrobial textile

Methodology Applied
Scientific EffectUV irradiation: Light

Implementation Method 3

contacting a textile with an inorganic base to produce a treated textile; contacting the rinsed textile with a solution comprising TiO2 nanoparticles at a concentration of 10-100 ppm, an alcohol, and an acid to form a coated textile

Methodology Applied
Scientific EffectSurface treatment: Adsorption

Data Source

PatentUS11746462B2Method for making antimicrobial article
Publication Date: 2023.09.05 IMAM ABDULRAHMAN BIN FAISAL UNIV
  • US11746462B2 patent drawing
  • US11746462B2 patent drawing
  • US11746462B2 patent drawing

AI summary

A method of making an antimicrobial textile comprising TiO2 nanoparticles is described. The TiO2 nanoparticles are immobilized by first treating a textile with a base, and then contacting with TiO2 nanoparticles in a solution of an alcohol and acid. The textile may be subsequently irradiated with UV light prior to use. The antimicrobial textile shows high effectiveness against the growth and proliferation of microorganisms transmitted within indoor environments.