Pneumatic Tire Sealant Adhesion via Release Agent Silicon

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Solution Overview

Problem

Existing methods for manufacturing pneumatic tires with sealant layers face challenges in achieving air retention properties and adhesiveness without compromising tire productivity, as they often result in poor adhesiveness between the tire inner surface and the sealant layer due to the use of release agents, leading to peeling issues and increased manufacturing time.

Innovation Solution

A pneumatic tire manufacturing method involving a bladder with a coating layer of release agent, where the amount of silicon in the release agent is between 0.1 wt.% to 10.0 wt.% ensures sufficient adhesiveness and air retention properties without deteriorating tire productivity, by transferring the release agent to the sealant layer during vulcanization, and using butyl and/or natural rubber for the sealant layer to enhance adhesiveness and prevent deformation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a release agent is applied to the inner surface of the green tire to prevent adhesion between the green tire and the bladder, then the green tire and bladder do not adhere, but the adhesiveness between the tire inner surface and the sealant layer deteriorates

Engineering Contradiction:
Improveadhesion prevention between green tire and bladderVSAvoidadhesiveness between tire inner surface and sealant layer
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies local quality by creating different surface conditions in different regions. The tire inner surface has a release agent layer in the shoulder region (for easy removal) and a release agent-free region in the tread region (for good sealant adhesion). This spatial differentiation resolves the contradiction between preventing bladder adhesion and ensuring sealant layer adhesiveness.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the tire inner surface into functionally distinct zones: a first region (shoulder portion) where the release agent remains to prevent bladder adhesion, and a second region (tread portion) where the release agent is removed to ensure sealant layer adhesiveness. This segmentation allows each region to optimize its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

2Strength

If buffing is performed on the tire inner surface to remove the release agent, then the release agent is removed and sealant layer adhesiveness is improved, but the gauge of the inner liner is thinned and air retention properties deteriorate

Engineering Contradiction:
Improveadhesiveness between tire inner surface and sealant layerVSAvoidair retention properties
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-defining the tire inner surface into regions with different release agent coverage before sealant layer application. The release agent is selectively removed from the tread portion region beforehand, creating an optimal bonding surface for the sealant layer without requiring post-vulcanization buffing that would thin the inner liner and compromise air retention.

Inventive Principle:
Principle #10Preliminary action

3Strength

If a film is preliminarily bonded to the inner surface of the green tire and the film is peeled off after vulcanization to remove the release agent, then the release agent is removed and sealant layer adhesiveness is improved, but manufacturing time increases

Engineering Contradiction:
Improveadhesiveness between tire inner surface and sealant layerVSAvoidmanufacturing time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The patent extracts the release agent removal step from the post-vulcanization process. Instead of bonding a film and peeling it off after vulcanization (which adds time), the invention directly creates release agent-free regions on the tire inner surface before sealant layer application, eliminating the film bonding and peeling steps while still achieving good sealant layer adhesiveness.

Inventive Principle:
Principle #2Taking out (Extraction)

4Strength

If the tire inner surface to which a release agent is adhered is cleaned, then the release agent is partially removed and sealant layer adhesiveness is improved, but the release agent cannot be sufficiently removed and tire productivity is poor

Engineering Contradiction:
Improveadhesiveness between tire inner surface and sealant layerVSAvoidtire productivity
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent applies local quality by creating distinct surface regions with different release agent coverage. Instead of attempting to completely clean the entire tire inner surface (which is time-consuming and ineffective), the invention selectively maintains the release agent in the shoulder region while creating release agent-free regions in the tread portion, achieving adequate sealant adhesion without sacrificing productivity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively maintains air retention and adhesiveness of the sealant layer while preventing productivity losses, as the release agent inhibits air permeation and ensures puncture sealing properties without the need for additional steps like buffing or film peeling, thereby stabilizing the sealant layer and maintaining tire uniformity.

Implementation Method 1

a pneumatic tire vulcanized using a bladder provided with a coating layer formed of a release agent

Methodology Applied
Scientific EffectTransfer of release agent during vulcanization: Deposition (physical)

Implementation Method 2

an adhesive sealant sticks to the foreign material so that the adhesive sealant is guided into a puncture hole

Methodology Applied
Scientific EffectAdhesive bonding: Adhesive

Implementation Method 3

a release agent is applied to the inner surface of the green tire to prevent the green tire and the bladder from adhering to each other

Methodology Applied
Scientific EffectRelease agent action: Lubrication

Data Source

PatentUS11701798B2Pneumatic tire and method of manufacturing same
Publication Date: 2023.07.18 THE YOKOHAMA RUBBER CO LTD
  • US11701798B2 patent drawing
  • US11701798B2 patent drawing
  • US11701798B2 patent drawing

AI summary

A pneumatic tire is vulcanized using a bladder provided with a coating layer formed of a release agent, and includes a sealant layer disposed on an inner surface of a tread portion in a tire circumferential direction. The amount of silicon of the release agents detected in at least a placement region of the sealant layer by fluorescence X-ray analysis is from 0.1 wt. % to 10.0 wt. %.