Titanium Alloy Composition for Fine β-Grains in Additive Manufacturing

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Solution Overview

Problem

Conventional methods for manufacturing titanium components, such as casting and forging, face challenges like high material waste, long lead times, and inability to produce complex shapes with refined grain structures, which affect the mechanical properties of the components.

Innovation Solution

The development of titanium alloys with specific compositions, including aluminum, molybdenum, and bismuth, that promote grain refinement and isotropic high-strength mechanical properties, particularly suited for direct energy deposition additive manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If additive manufacturing is used to manufacture titanium components, then productivity is improved and material waste is reduced, but the grain structure becomes coarse and mechanical properties deteriorate

Engineering Contradiction:
Improvemanufacturing speedVSAvoidgrain structure refinement
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameters of the titanium alloy by adding specific elements (Nb: 1-5 wt%, Mo: 1-4 wt%, W: 1-4 wt%, Ta: 1-3 wt%) to modify the solidification behavior and achieve fine grain structure through compositional control rather than mechanical processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a multi-element composite titanium alloy system combining α-stabilizers (Al, Sn, Zr), β-stabilizers (Nb, Mo, W, Ta, V), and other elements to achieve synergistic effects that refine grain structure while maintaining the benefits of additive manufacturing

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional thermo-mechanical processing is used to refine grain structure, then mechanical properties are improved, but the manufacturing complexity and lead time increase

Engineering Contradiction:
Improvemechanical strengthVSAvoidprocessing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent replaces mechanical grain refinement methods (forging, rolling, extrusion) with chemical composition control that enables spontaneous fine grain formation during additive manufacturing solidification, eliminating the need for complex thermo-mechanical processing equipment and steps

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If mechanical deformation is applied to recrystallize grains in additive manufactured components, then grain structure is refined, but the effective deposition rate decreases

Engineering Contradiction:
Improvegrain structureVSAvoiddeposition rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent performs preliminary grain refinement through chemical composition design before the additive manufacturing process begins, so that fine grains form automatically during solidification without requiring subsequent mechanical deformation steps that would reduce deposition rate

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these titanium alloys results in components with significantly refined prior β-grain sizes, improved strength, fatigue resistance, and isotropic properties, overcoming the limitations of traditional manufacturing methods.

Implementation Method 1

the low surface tension element Bi

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

promote grain refinement

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 3

solidifies and cools down

Methodology Applied
Scientific EffectSolidification: Freezing

Data Source

PatentEP4516433A1Titanium-base alloy compositions
Publication Date: 2025.03.05 NORSK TITANIUM AS
  • EP4516433A1 patent drawingFigure 1A~1B
  • EP4516433A1 patent drawingFigure 2A~2C
  • EP4516433A1 patent drawingFigure 3A~3C

AI summary

The present invention relates to titanium alloy compositions suited for manufacturing components by additive manufacturing, resulting in components that exhibit relatively small prior β-grain sizes. The titanium alloy compositions comprises: from 2 to 7 wt% Al, from 1.5 to 6 wt% Mo, from 0.25 to 1.5 wt% Bi, unavoidable impurities, and a remaining wt% Ti which makes the total content of constituents in the titanium alloy composition sum up to 100 wt%, wherein the weight percentages are based on the total mass of the titanium alloy composition.