Titanium Complex Curing Catalyst for Safe, Stable Moisture Curing

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Solution Overview

Problem

Existing curing catalysts for silicone-based and modified silicone-based rubber compositions, such as tin carboxylate compounds, titanium acid ester compounds, and quaternary ammonium salts, face issues with safety, environmental pollution, and inconsistent curing rates due to moisture and humidity, leading to unstable cured products.

Innovation Solution

A curing catalyst composed of a titanium compound complexed with ammonium hydroxide, with a specific molar ratio, is used to enhance the curing rate of polymers with reactive hydrolyzable silicon-containing groups, ensuring high safety and practical curing performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If tin carboxylate compounds or alkyltin salt compounds are used as curing catalysts, then the curing rate is improved, but safety and environmental pollution deteriorate due to endocrine disruptor effects

Engineering Contradiction:
Improvecuring rateVSAvoidsafety and environmental pollution
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces persistent toxic catalysts (tin compounds) with a more benign alternative (titanium compound complex) that achieves the curing function without long-term environmental harm. The titanium compound complex serves as a single-use catalyst that decomposes after facilitating the curing reaction, avoiding the accumulation of toxic substances in the environment while maintaining effective curing rates.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent introduces a complexing agent that forms a complex with the titanium compound, creating an intermediary substance that mediates the curing reaction. This complex acts as a bridge between the catalyst and the polymer, enabling effective catalysis while reducing the toxicity concerns associated with traditional tin-based catalysts. The complex structure allows the titanium compound to function as a catalyst without directly exposing the system to toxic tin substances.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If titanium acid ester compounds are used as catalysts, then the curing rate is improved, but stability deteriorates due to decomposition by moisture and humidity variation

Engineering Contradiction:
Improvecuring rateVSAvoidstability of cured product
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the chemical parameters of the titanium compound by complexing it with a specific agent, changing its physical and chemical properties. This parameter change makes the catalyst less sensitive to moisture and humidity variations. The complexed titanium compound maintains its catalytic activity while becoming more stable against decomposition, allowing consistent curing performance across different humidity conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite catalyst system by combining the titanium compound with a complexing agent. This composite structure provides the benefits of both components: the titanium compound provides catalytic activity for high curing rates, while the complexing agent provides stability against moisture and humidity. The composite catalyst achieves a balance between reactivity and stability that neither component could achieve alone.

Inventive Principle:
Principle #40Composite materials

3Object-affected harmful factors

If carboxylic acid and amine combined catalyst is used, then safety is improved by avoiding endocrine disruptors, but curing rate deteriorates to insufficient levels

Engineering Contradiction:
ImprovesafetyVSAvoidcuring rate
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent changes the chemical parameters of the safe catalyst system by using a titanium compound complex instead of the carboxylic acid-amine combination. This parameter change significantly enhances the curing rate while maintaining safety benefits. The titanium compound complex provides higher catalytic activity compared to the acid-amine system, achieving practical curing rates without compromising safety or introducing endocrine disruptors.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst provides a high curing rate and stable curing process, producing safe and durable cured products without the drawbacks of previous catalysts, suitable for one-pack type moisture-curable compositions.

Implementation Method 1

a catalyst composition obtained by forming a complex by reacting a titanium compound (B1) with an ammonium hydroxide (B2)

Methodology Applied
Scientific EffectComplex formation: Chemical Bonding

Implementation Method 2

A curing catalyst is used to accelerate the curing process in this reaction

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

the reaction mechanism of the process in which the silicone-based rubber and the modified silicone-based rubber become a cured product is based on a condensation reaction or an addition reaction of a reactive hydrolyzable silicon-containing group in the presence of water

Methodology Applied
Scientific EffectCondensation reaction: Chemical Bonding

Implementation Method 4

a reactive hydrolyzable silicon-containing group

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS12516157B2Curing catalyst used for curing polymer, method for producing same, moisture-curable composition, and method for producing cured product
Publication Date: 2026.01.06 NITTO KASEI CO LTD
  • US12516157B2 patent drawing
  • US12516157B2 patent drawing
  • US12516157B2 patent drawing

AI summary

Provided is a curing catalyst having a high safety and a practical curing rate.According to the present invention, provided is a curing catalyst [B] used for curing a polymer [A] having a reactive hydrolyzable silicon-containing group, whereinthe curing catalyst [B] contains a catalyst composition obtained by forming a complex by reacting a titanium compound [B1] with an ammonium hydroxide [B2] in a mixture obtained by mixing the titanium compound [B1] and the ammonium hydroxide [B2],a molar ratio of the titanium compound [B1] to the ammonium hydroxide [B2] in the mixture is 1 to 2.8,the titanium compound [B1] is represented by Chemical Formula (1),the ammonium hydroxide [B2] is represented by Chemical Formula (2).