Microwave Plasma Spheroidization of Titanium Hydride Alloy Powder

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Solution Overview

Problem

Conventional spheroidization methods using thermal arc and radio-frequency generated plasmas suffer from electrode degradation, non-uniform temperature profiles, and incomplete spheroidization of metal powders, leading to contamination and high production costs due to complex multi-step processes.

Innovation Solution

A microwave generated plasma torch apparatus is used to simultaneously dehydrogenate and spheroidize metal and metal alloy particles, eliminating separate dehydrogenation and deoxidation steps, and providing a continuous process that reduces contamination and energy consumption while achieving high consistency and uniformity in the final product.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If thermal arc plasma is used for spheroidization, then high temperature melting is achieved, but electrode degradation occurs causing contamination and non-uniform temperature distribution

Engineering Contradiction:
Improveplasma temperatureVSAvoidelectrode degradation and contamination
Core Design Contradiction:
TemperatureVSObject-generated harmful factors

Solution Approach 1:

The harmful electrodes are completely removed from the plasma generation system. The patent uses a wireless energy transfer mechanism where power is transmitted through a waveguide into the plasma chamber without physical electrode contact, thereby extracting the contamination source while maintaining high-temperature plasma for spheroidization

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

A dielectric waveguide acts as an intermediary to transmit electromagnetic energy into the plasma chamber without direct material contact. This mediator enables high-temperature plasma generation while preventing electrode degradation and contamination of the powder particles

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If thermal arc plasma with side injection is used, then powder melting is achieved, but non-uniform temperature exposure results in incomplete spheroidization

Engineering Contradiction:
Improvespheroidization uniformityVSAvoidtemperature uniformity
Core Design Contradiction:
Manufacturing precisionVSTemperature

Solution Approach 1:

The plasma chamber is designed to create a uniform temperature field throughout the processing zone. By using volumetric heating through electromagnetic energy deposition, all regions of the plasma achieve similar temperatures, ensuring uniform heat exposure to all powder particles regardless of their position in the chamber

Inventive Principle:
Principle #12Equipotentiality

3Temperature

If radio-frequency inductively coupled plasma is used, then plasma generation is achieved, but non-uniform magnetic field creates temperature gradients and capacitive effects causing arcing and contamination

Engineering Contradiction:
Improveplasma temperatureVSAvoidplasma uniformity and stability
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The mechanical/electromagnetic coil-based plasma generation system is replaced with a waveguide-based electromagnetic energy transfer system. This substitution eliminates the non-uniform magnetic field and capacitive effects inherent in RF coil systems, providing more uniform plasma heating without arcing or dielectric degradation

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The method changes the fundamental parameter of energy coupling from magnetic induction (RF coils) to direct electromagnetic wave propagation (waveguide). This parameter change results in more uniform energy distribution throughout the plasma volume, eliminating temperature gradients and stabilizing plasma composition

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If conventional multi-step processes (HDH plus spheroidization) are used, then dehydrogenation and spheroidization are achieved, but process complexity and production time increase

Engineering Contradiction:
Improvepowder qualityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent combines multiple processing functions (dehydrogenation, spheroidization, and potential deoxidation) into a single integrated plasma processing step. Powder particles undergo all necessary transformations simultaneously in the uniform plasma environment, eliminating the need for separate HDH and spheroidization equipment and processes

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves over 90% spheroidization efficiency, reduces production costs, and maintains the original particle size distribution, resulting in consistent and high-quality spherical metal and metal alloy powders suitable for additive manufacturing and powdered metallurgy applications.

Implementation Method 1

introducing a metal hydride feed material into a microwave generated plasma

Methodology Applied
Scientific EffectMicrowave radiation heating: Microwave Radiation

Implementation Method 2

melting, dehydrogenating, and spheroidizing the feed material within the plasma

Methodology Applied
Scientific EffectPlasma thermal energy: Plasma

Implementation Method 3

Surface tension of the melt pulls it into a spherical shape

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Data Source

PatentEP4324577A1Method of producing spheroidal dehydrogenated titanium alloy particles
Publication Date: 2024.02.21 6K INC
  • EP4324577A1 patent drawingFigure 1
  • EP4324577A1 patent drawingFigure 2
  • EP4324577A1 patent drawingFigure 3

AI summary

Methodologies, systems, and devices are provided for producing metal spheroidal powder products. Dehydrogenated and spheroidized particles are prepared using a process including introducing a metal hydride feed material into a plasma torch. The metal hydride feed material is melted within a plasma in order to dehydrogenate and spheroidize the materials, forming dehydrogenated and spheroidized particles. The dehydrogenated and spheroidized particles are then exposed to an inert gas and cooled in order to solidify the particles into dehydrogenated and spheroidized particles. The particles are cooled within a chamber having an inert gas.