Titanium Surface Laser Oxidation for Consistent Adhesive Bonding

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Solution Overview

Problem

The bond quality of titanium substrates treated with traditional methods like grit blast, alkaline etching, and acid or basic anodizing is inconsistent, and the natural oxide layer formed on titanium substrates in an oxygen environment is poorly bonded, leading to undesirable adhesive bonding surfaces.

Innovation Solution

Applying energy from a fiber laser system to create a nanoscale open porous oxide layer on contoured titanium substrates, which allows adhesives to infiltrate and enhance bonding performance, while also removing contaminants and preexisting oxide layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional methods like grit blast, alkaline etching, or acid anodizing are used to prepare titanium substrate surfaces, then surface roughness and oxide layer formation are achieved, but bond quality consistency deteriorates

Engineering Contradiction:
Improvesurface preparation consistencyVSAvoidbond quality consistency
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent replaces traditional mechanical surface preparation methods (grit blasting) and wet chemistry processes (alkaline etching, acid anodizing) with a laser-based system. The laser delivers controlled energy to the titanium substrate surface, creating consistent oxide layers and micro-roughness through photothermal effects, thereby eliminating the variability inherent in mechanical and chemical methods while improving bond quality consistency.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes laser parameters (power, pulse duration, scanning speed, wavelength) to precisely control the surface treatment process. By adjusting these parameters, the system creates optimal oxide layer thickness and surface micro-roughness for adhesive bonding. This parametric control enables repeatable results that traditional methods cannot achieve, resolving the contradiction between manufacturing precision and bond quality consistency.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If wet chemistry batch processes like alkaline etching or acid anodizing are used, then oxide layer formation is achieved, but chemical solution consumption and environmental hazards increase

Engineering Contradiction:
Improveoxide layer formationVSAvoidchemical solution hazards
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent replaces wet chemistry processes with a laser-based photothermal system. The laser energy directly transforms titanium substrate surface properties through controlled heating, forming oxide layers without requiring hazardous chemical solutions. This substitution eliminates environmental hazards and chemical waste while maintaining oxide layer formation quality.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The laser beam acts as an intermediary that transfers energy to the titanium substrate surface without requiring direct contact with chemical solutions. This energy transfer mechanism achieves oxide layer formation through controlled thermal effects, bypassing the need for hazardous chemicals entirely while maintaining manufacturing precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If natural oxide layers form on titanium substrates in oxygen environments, then oxide layer formation occurs, but adhesive bonding performance deteriorates

Engineering Contradiction:
Improveoxide layer formationVSAvoidadhesive bonding strength
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent uses laser parameters to transform the natural oxide layer into an optimized bonding surface. The laser creates controlled micro-roughness and modifies oxide layer properties (thickness, composition, porosity) that dramatically improve adhesive infiltration and mechanical interlocking. This parametric control converts the naturally formed but poorly bonded oxide layer into a high-strength bonding surface.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The laser treatment creates a porous micro-structure within the oxide layer that enables deep adhesive infiltration. This porous morphology, formed through controlled laser heating and oxidation, provides mechanical interlocking that significantly enhances adhesive bonding strength compared to dense natural oxide layers.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces a consistent and durable bond with improved adhesive infiltration and mechanical interlocking, leading to enhanced bond performance and crack resistance compared to traditional surface preparation techniques.

Implementation Method 1

applying energy from a fiber laser system to create a nanoscale open porous oxide layer on contoured titanium substrates

Methodology Applied
Scientific EffectLaser: Laser

Implementation Method 2

The laser energy is distributed to the contoured titanium surface by at least one of direct light of sight, reflection, or scattering

Methodology Applied
Scientific EffectLaser heating: Heating

Implementation Method 3

The energy applied from the fiber laser system to the surface of the titanium substrate to create the produced oxide layer may also remove one or more contaminants present on the surface of the titanium substrate

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS11534863B2Method for adhesive bonding of titanium components using a fiber laser system
Publication Date: 2022.12.27 RTX CORP
  • US11534863B2 patent drawing
  • US11534863B2 patent drawing
  • US11534863B2 patent drawing

AI summary

A method for treating a surface of a contoured titanium substrate used for adhesively bonded engine components. The method including applying energy from a fiber laser system to a contoured surface of a titanium substrate, the laser energy is distributed to the contoured titanium surface by at least one of direct light of sight, reflection, or scattering of one or more laser beam.