Titanium oxide composite fibers and method for producing same

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Solution Overview

Problem

The existing methods for internally adding titanium oxide to fibers face challenges in achieving a high fixation ratio without using fixing agents, which limits the whiteness and hiding power of the resulting composite fibers.

Innovation Solution

A titanium oxide composite fiber is created by firmly fixing titanium oxide to fibers using an inorganic binder, such as hydrotalcite, which is synthesized in a slurry containing the fibers and titanium oxide, ensuring efficient and uniform fixation of titanium oxide.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fixing agents such as aluminum sulfate or cationic polyacrylamide are used to increase the fixation ratio of titanium oxide in fiber, then the fixation ratio of titanium oxide is improved, but the complexity of the manufacturing process and the use of chemical additives increase

Engineering Contradiction:
Improvefixation ratio of titanium oxideVSAvoidcomplexity of manufacturing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the need for fixing agents from the manufacturing process. By using an inorganic binder that naturally forms during the fiber production process, the patent removes the requirement for additional fixing agents like aluminum sulfate or cationic polyacrylamide, thereby simplifying the manufacturing process while maintaining high fixation ratios of titanium oxide.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention introduces an inorganic binder as an intermediary substance between titanium oxide and fiber. This binder, which may include metal oxides such as zinc oxide, calcium oxide, or magnesium oxide, serves as a mediating agent that facilitates the binding of titanium oxide to the fiber without requiring complex fixing agents, thus resolving the contradiction between fixation ratio and process complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If fixing agents are used to achieve high fixation ratio of titanium oxide, then the whiteness and hiding power are improved, but the cost and environmental impact increase due to chemical additives

Engineering Contradiction:
Improvewhiteness and hiding powerVSAvoidenvironmental impact of chemical additives
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention converts potentially harmful chemical additives into beneficial inorganic binders. By using metal oxides such as zinc oxide, calcium oxide, or magnesium oxide as binders, the patent transforms substances that could be considered chemical contaminants into useful binding agents that enhance whiteness and hiding power while reducing environmental impact. These inorganic binders are generally more environmentally friendly than organic fixing agents.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention changes the chemical parameters of the binding system by replacing organic fixing agents with inorganic binders. This parameter change involves using metal oxides with different chemical properties that are more environmentally benign, thereby maintaining the desired whiteness and hiding power while reducing the environmental harm associated with traditional fixing agents.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If titanium oxide is internally added to fiber without fixing agents, then the manufacturing process is simplified, but the fixation ratio and uniformity of titanium oxide distribution deteriorate

Engineering Contradiction:
Improvesimplicity of manufacturing processVSAvoiduniformity of titanium oxide distribution
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The inorganic binder acts as an intermediary that enables uniform distribution of titanium oxide without complicating the manufacturing process. The binder provides a matrix or framework that holds titanium oxide particles uniformly throughout the fiber structure, achieving good distribution uniformity while maintaining the simplicity of the manufacturing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite material system consisting of fiber, inorganic binder, and titanium oxide. This composite structure allows the different components to work together synergistically, where the inorganic binder provides both the binding function and the uniform distribution medium for titanium oxide, thereby achieving good manufacturing precision without sacrificing ease of manufacture.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a composite fiber with high ash yield, uniform dispersion, and enhanced whiteness and hiding power, surpassing the limitations of traditional methods by maintaining titanium oxide on the fiber surface without the need for fixing agents.

Implementation Method 1

an inorganic binder, at least part of the inorganic binder containing at least one inorganic compound selected from (i) an inorganic salt containing at least one of: at least one metal selected from magnesium, barium, aluminum, copper, iron, and zinc; and silicic acid and (ii) metal particles containing the at least one metal, the inorganic binder being firmly fixed to the fiber, the titanium oxide being firmly fixed to the inorganic binder

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

generating the titanium oxide composite fiber by synthesizing an inorganic binder in the slurry to which the titanium oxide has been added

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Data Source

PatentUS11390997B2Titanium oxide composite fibers and method for producing same
Publication Date: 2022.07.19 NIPPON PAPER IND CO LTD
  • US11390997B2 patent drawing
  • US11390997B2 patent drawing
  • US11390997B2 patent drawing

AI summary

The present invention provides a titanium oxide composite fiber in which titanium oxide is efficiently fixed in fiber, and a method for producing the titanium oxide composite fiber. A composite fiber of the present invention includes: fiber; titanium oxide; and an inorganic binder, at least part of the inorganic binder containing at least one inorganic compound selected from (i) an inorganic salt containing at least one of: at least one metal selected from magnesium, barium, aluminum, copper, iron, and zinc; and silicic acid and (ii) metal particles containing the at least one metal, the titanium oxide being firmly fixed to the fiber via the inorganic binder.