Titanium-Zirconia Brazed Assembly Without Ceramic Metallization

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Solution Overview

Problem

The assembly of ceramic and metal alloy components in timepieces faces challenges with existing methods, such as mechanical stress and polymer adhesives, which compromise long-term adherence and mechanical properties.

Innovation Solution

A controlled atmosphere brazing method is employed, where recesses are created in the ceramic component, filled with braze material, and aligned with a titanium alloy component, then heated to form a strong bond without prior metallization, using a compatible braze material like CF CuMn3 in an argon furnace.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If press fit, adhesive bonding or screw fit is used to assemble ceramic and metal alloy components, then assembly is achieved, but long-term adherence is compromised and mechanical properties are weakened

Engineering Contradiction:
Improvelong-term adherenceVSAvoidmechanical properties
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention changes the bonding mechanism from mechanical (press fit, screw fit) or chemical (adhesive bonding) to metallurgical bonding through brazing. By controlling the brazing temperature parameters and using a eutectic braze material, the assembly achieves both strong mechanical properties and reliable long-term adherence, resolving the contradiction between these two requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite braze material composition (e.g., CF CuMn3 or similar eutectic alloys) that combines multiple elements to achieve optimal bonding characteristics. This composite braze material provides both the strength needed for mechanical integrity and the adhesion properties for long-term reliability, simultaneously addressing both requirements.

Inventive Principle:
Principle #40Composite materials

2Reliability

If prior metallization is applied to ceramic surfaces before brazing, then braze compatibility is improved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvebraze compatibilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the metallization step from the traditional brazing process. By selecting a braze material that is compatible with both ceramic and titanium alloy surfaces, the process directly brazes the components without requiring intermediate metallization layers, thereby reducing manufacturing complexity while maintaining braze compatibility.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The braze material itself acts as an intermediary that directly bonds to both ceramic and titanium alloy surfaces. By choosing a suitable braze composition (such as copper-based eutectic alloys), it serves as the mediating layer between the two dissimilar materials, eliminating the need for separate metallization steps while ensuring compatible bonding to both materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If controlled atmosphere brazing is used to achieve strong bonding, then assembly quality is improved, but process complexity increases

Engineering Contradiction:
Improveassembly qualityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention employs controlled atmosphere brazing using an inert or reducing atmosphere to prevent oxidation of the titanium alloy and braze material during the high-temperature bonding process. This controlled environment ensures high assembly quality by preventing surface defects and ensuring clean metallurgical bonding, while the use of standard furnace equipment keeps the added complexity manageable.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves durable and high-quality assemblies with improved mechanical and thermal properties, ensuring long-term adherence and reducing material costs by eliminating mechanical stress and polymer adhesives.

Implementation Method 1

heating in a controlled atmosphere to a temperature higher than the melting temperature of the braze material to form the braze

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

heating in a controlled atmosphere to a temperature higher than the melting temperature of the braze material

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Data Source

PatentUS11498879B2Method for brazing titanium alloy components with zirconia-based ceramic components for horology or jewellery
Publication Date: 2022.11.15 COMADUR
  • US11498879B2 patent drawing
  • US11498879B2 patent drawing

AI summary

A method for brazing a first ceramic component and a second metal alloy component, to make a structural or external timepiece element, a zirconia-based ceramic is chosen for the first component and a titanium alloy for the second component, a first recess is made inside the first component, set back from a first surface in a junction area with a second surface of the second component, braze material is deposited on this first surface and inside each recess, the second surface is positioned in alignment with the first surface to form an assembly, this assembly is heated in a controlled atmosphere to above the melting temperature of the braze material, in order to form the braze in the junction area.