TMD Thin Film Buffer Structure for Low-Temperature Direct Growth

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Solution Overview

Problem

Existing methods for synthesizing transition metal dichalcogenides (TMDs) using high temperatures or catalysts make them unsuitable for semiconductor processes.

Innovation Solution

A thin film structure comprising a first buffer layer, a transition metal dichalcogenide layer, and a second buffer layer, where the second buffer layer includes the same chalcogen element as the transition metal dichalcogenide layer, is manufactured using a non-catalytic direct growth method at low temperature through heat treatment or plasma treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If high temperature or catalyst methods are used to synthesize TMDs, then synthesis is achieved, but the method becomes unsuitable for semiconductor processes

Engineering Contradiction:
Improvesuitability for semiconductor processesVSAvoidsynthesis temperature
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent changes the temperature parameter from high temperature (unsuitable for semiconductors) to low temperature (suitable for semiconductors) by using a buffer layer-mediated synthesis mechanism that enables TMD formation at lower temperatures through chemical reactions with the buffer layer

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The buffer layer acts as an intermediary substance that mediates the synthesis process. It provides chalcogen elements to react with the metal layer, enabling TMD formation without requiring high temperatures or catalysts, thus making the process suitable for semiconductor manufacturing

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If conventional synthesis methods are used, then TMDs can be synthesized, but thickness uniformity is poor

Engineering Contradiction:
Improvethickness uniformityVSAvoidsynthesis process
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The buffer layer serves as a mediator that ensures uniform thickness of the synthesized TMD layer. By controlling the buffer layer thickness and composition, the reaction proceeds uniformly across the substrate, producing TMDs with improved thickness uniformity suitable for semiconductor devices

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent controls synthesis parameters including buffer layer thickness, metal layer composition, and annealing conditions to achieve uniform TMD thickness. By optimizing these parameters, the method produces high-quality TMD films with consistent thickness across the substrate area

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the direct growth of TMDs without the need for high temperatures or catalysts, improving bonding strength and enabling the synthesis of TMDs with improved thickness uniformity, suitable for semiconductor devices.

Implementation Method 1

a transition metal dichalcogenide layer synthesized by replacing oxygen in a transition metal oxide layer with a chalcogen element

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

direct growth method at low temperature through heat treatment or plasma treatment

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 3

direct growth method at low temperature through heat treatment or plasma treatment

Methodology Applied
Scientific EffectPlasma treatment: Plasma

Implementation Method 4

forming a plurality of grain boundaries by crystallizing the first buffer layer and the second buffer layer

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS20250120150A1Thin film structure and method of manufacturing the thin film structure
Publication Date: 2025.04.10 SAMSUNG ELECTRONICS CO LTD
  • US20250120150A1 patent drawing
  • US20250120150A1 patent drawing
  • US20250120150A1 patent drawing

AI summary

A thin film structure according to various example embodiments includes a first buffer layer, a transition metal dichalcogenide layer on the first buffer layer, and a second buffer layer on the transition metal dichalcogenide layer, wherein the second buffer layer includes same chalcogen element as a chalcogen element included in the transition metal dichalcogenide layer.