TMR Device bcc NiFe Insertion Layer Epitaxy

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Solution Overview

Problem

TMR devices with MgO tunneling barriers face challenges in achieving high tunneling magnetoresistance (TMR) while maintaining low magnetostriction and damping, as the fcc NiFe layer disrupts epitaxial relationships and increases thermal-induced magnetic noise.

Innovation Solution

Incorporating a body-centered-cubic (bcc) NiFe insertion layer between the CoFeB and fcc NiFe layers, along with an optional amorphous separation layer, to maintain (001) crystalline formation of the MgO and CoFeB layers, reducing Gilbert damping and increasing TMR.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If an fcc NiFe compensation layer is used to reduce magnetostriction, then magnetostriction is reduced, but the epitaxial relationship between MgO and CoFeB is disrupted and Gilbert damping increases

Engineering Contradiction:
ImprovemagnetostrictionVSAvoidTMR signal quality
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The NiFe layer is segmented into two distinct layers: an fcc NiFe compensation layer for controlling magnetostriction and a bcc NiFe insertion layer for maintaining epitaxial relationships. This segmentation allows each layer to independently fulfill its specific function without interfering with the other, resolving the contradiction between magnetostriction control and TMR signal quality.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The bcc NiFe insertion layer acts as an intermediary between the MgO barrier layer/CoFeB layer and the fcc NiFe compensation layer. It maintains the (001) epitaxial relationship and promotes high-quality crystallization while the fcc NiFe layer provides magnetostriction compensation, thus mediating between structural integrity and magnetic property control.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If the fcc NiFe layer is placed directly adjacent to CoFeB, then magnetostriction compensation is achieved, but thermal-induced magnetic noise increases due to high Gilbert damping

Engineering Contradiction:
Improvemagnetostriction compensationVSAvoidthermal-induced magnetic noise
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The NiFe layer is divided into two functional segments: the fcc NiFe compensation layer that provides magnetostriction control and the bcc NiFe insertion layer that suppresses thermal-induced magnetic noise by maintaining low Gilbert damping through preserved epitaxial relationships.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The bcc NiFe insertion layer serves as a protective intermediary between the CoFeB layer and the fcc NiFe compensation layer, preventing the fcc structure from disrupting the epitaxial relationship and thereby reducing thermal-induced magnetic noise while still allowing magnetostriction compensation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If MgO barrier layer is annealed to achieve (001) epitaxy, then TMR is enhanced, but the presence of fcc NiFe disrupts crystalline formation

Engineering Contradiction:
ImproveTMRVSAvoidcrystalline structure formation
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The NiFe layer is segmented into a bcc NiFe insertion layer that promotes (001) epitaxial crystallization during annealing and an fcc NiFe compensation layer that provides magnetostriction control. The bcc layer's crystal structure is compatible with MgO (001) epitaxy, enabling high-quality crystalline formation while the fcc layer maintains its magnetostriction compensation function.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The bcc NiFe insertion layer acts as a mediator during the annealing process, facilitating the formation of (001) epitaxial relationships between MgO and CoFeB by providing a compatible crystal structure, while the fcc NiFe layer maintains magnetostriction compensation without interfering with the crystallization process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The bcc NiFe insertion layer enhances TMR and lowers the Gilbert damping constant, improving the signal-to-noise ratio by reducing thermal noise, while maintaining the desired crystalline structure.

Implementation Method 1

The bcc NiFe insertion layer (and the optional amorphous separation layer if it is used) prevents the fcc NiFe layer from adversely affecting the (001) crystalline formation of the MgO and CoFeB layers

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 2

The MgO barrier layer is typically formed by sputter deposition and subsequent annealing, which forms the crystalline structure

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 3

The barrier layer is typically made of a metallic oxide that is so sufficiently thin that quantum-mechanical tunneling of charge carriers occurs between the two ferromagnetic layers

Methodology Applied
Scientific EffectQuantum tunneling:

Implementation Method 4

The quantum-mechanical tunneling process is electron spin dependent, which means that an electrical resistance measured when applying a sense current across the junction depends on the spin-dependent electronic properties

Methodology Applied
Scientific EffectMagnetoresistance: Magnetoresistance

Implementation Method 5

The MgO barrier layer is typically formed by sputter deposition and subsequent annealing, which forms the crystalline structure

Methodology Applied
Scientific EffectSputter deposition: Sputtering

Data Source

PatentUS9177573B1Tunneling magnetoresistive (TMR) device with magnesium oxide tunneling barrier layer and free layer having insertion layer
Publication Date: 2015.11.03 WESTERN DIGITAL TECHNOLOGIES INC
  • US9177573B1 patent drawing
  • US9177573B1 patent drawing
  • US9177573B1 patent drawing

AI summary

A tunneling magnetoresistance (TMR) device has a thin MgO tunneling barrier layer and a free ferromagnetic multilayer. The free ferromagnetic multilayer includes a CoFeB first ferromagnetic layer, a face-centered-cubic (fcc) NiFe compensation layer with negative magnetostriction, and a body-centered-cubic (bcc) NiFe insertion layer between the CoFeB layer and the fcc NiFe compensation layer. An optional ferromagnetic nanolayer may be located between the MgO barrier layer and the CoFeB layer. An optional amorphous separation layer may be located between the CoFeB layer and the bcc NiFe insertion layer. The bcc NiFe insertion layer (and the optional amorphous separation layer if it is used) prevents the fcc NiFe layer from adversely affecting the crystalline formation of the MgO and CoFeB layers during annealing. The bcc NiFe insertion layer also increases the TMR and lowers the Gilbert damping constant of the free ferromagnetic multilayer.