Toner External Additives for Image Quality in High Humidity

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Solution Overview

Problem

In electrophotography, electrostatic charge image developing toners face issues with image defects such as color streaks and fogging due to toner filming and electric charge leakage, especially in high-temperature and high-humidity environments, where silicone oil-based additives absorb moisture and cause electrical charge leakage.

Innovation Solution

Incorporating inorganic particles with saturated hydrocarbons having 9 to 35 carbon atoms as external additives, which have low moisture absorbency and reduce the coefficient of friction, thereby preventing toner filming and electric charge leakage by ensuring the hydrocarbons are physically adsorbed onto the particles' surfaces, covering at least 50% of the surface area.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If silicone oil-based additives are used in toner, then fluidity and cleaning property are improved, but moisture absorbency increases causing electric charge leakage and image defects in high-temperature and high-humidity environments

Engineering Contradiction:
Improvefluidity and cleaning propertyVSAvoidelectrical charge stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent changes the chemical composition parameter of the external additive from silicone oil-based to inorganic particles with saturated hydrocarbons (9-35 carbon atoms). This parameter change maintains the desired fluidity and cleaning properties while fundamentally altering the moisture interaction characteristics, eliminating the electric charge leakage problem that occurred with silicone oil in high-temperature and high-humidity environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite external additive by coating inorganic particles (such as silica, alumina, or titanium oxide) with saturated hydrocarbons having 9-35 carbon atoms. This composite structure combines the low moisture absorbency and electrical stability of inorganic particles with the surface properties of saturated hydrocarbons that provide good fluidity and cleaning performance, resolving the contradiction between operational ease and reliability.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If external additives are added to toner particles, then fluidity is improved, but toner filming occurs causing color streaks and image defects

Engineering Contradiction:
ImprovefluidityVSAvoidtoner filming
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent changes the parameter of the external additive from organic silicone oil to inorganic particles with hydrocarbon coating. This parameter change reduces the adhesive properties that cause toner filming while maintaining sufficient fluidity through the hydrocarbon coating, thereby preventing color streaks and image defects.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The inorganic particles with saturated hydrocarbon coating act as a sacrificial layer that prevents toner-to-toner adhesion. The coating provides a low-friction surface that allows toner particles to move freely without forming films, effectively preventing the harmful object-generated effect of toner filming.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of inorganic particles with saturated hydrocarbons effectively suppresses image defects like color streaks and fogging, maintaining image quality even in challenging environmental conditions by preventing toner attachment and electric charge leakage.

Implementation Method 1

ensuring the hydrocarbons are physically adsorbed onto the particles' surfaces, covering at least 50% of the surface area

Methodology Applied
Scientific EffectPhysical adsorption: Adsorption

Implementation Method 2

reduce the coefficient of friction, thereby preventing toner filming and electric charge leakage

Methodology Applied
Scientific EffectFriction reduction: Friction

Data Source

PatentUS8741516B2Electrostatic charge image developing toner, electrostatic charge image developer, toner cartridge, developer cartridge, process cartridge, image forming apparatus, and image forming method
Publication Date: 2014.06.03 FUJIFILM BUSINESS INNOVATION CORP
  • US8741516B2 patent drawing

AI summary

An electrostatic charge image developing toner includes toner particles containing a colorant, a binder resin, and a release agent and an external additive, in which the external additive contains inorganic particles which include saturated hydrocarbons having from 9 to 35 carbon atoms on the surfaces thereof.