Electrostatic Toner Composite Core Shell Layer Hot Offset

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Solution Overview

Problem

Conventional electrostatic latent image developing toners face issues with adhesiveness and chargeability, leading to carrier contamination and image quality deterioration, especially in high-temperature and high-humidity environments, due to excessive releasing agent precipitation and low elasticity.

Innovation Solution

The toner particles comprise a composite core with a shell layer and organic particles, where the shell layer has a glass transition point of 50-90°C and the organic particles contain a releasing agent with a glass transition point of 90-110°C, ensuring the releasing agent is supplied to the core during fixing and maintaining chargeability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a releasing agent is added to improve releasability, then hot offset is reduced, but the releasing agent precipitates excessively in high-temperature and high-humidity environments, causing adhesiveness issues and carrier contamination

Engineering Contradiction:
Improvehot offsetVSAvoidreleasing agent precipitation
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent changes the glass transition temperature parameter of the resin from conventional values to specifically 50-90°C, and the releasing agent's glass transition temperature to 90-110°C. This parameter optimization allows the releasing agent to remain stable and non-precipitating in high-temperature environments while still providing effective releasability, thus reducing hot offset without causing excessive precipitation or carrier contamination

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure where resin fine particles containing the releasing agent are combined with a binder resin. The resin has a glass transition point of 50-90°C and the releasing agent has a glass transition point of 90-110°C. This composite material approach ensures that the releasing agent is properly dispersed and stabilized within the resin matrix, preventing precipitation while maintaining releasability and reducing hot offset

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the toner has low elasticity to improve fixability, then low-temperature fixability is enhanced, but adhesiveness increases causing carrier contamination and image quality deterioration

Engineering Contradiction:
Improvelow-temperature fixabilityVSAvoidcarrier contamination
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the glass transition temperature parameter of the resin to 50-90°C, which provides the right balance of elasticity and adhesiveness. This parameter change enables the toner to have sufficient elasticity for good low-temperature fixability while maintaining controlled adhesiveness that prevents carrier contamination and image quality deterioration

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If the resin glass transition point is lowered to improve low-temperature fixability, then fixing at lower temperatures becomes possible, but the toner loses elasticity and becomes too adhesive

Engineering Contradiction:
Improvelow-temperature fixabilityVSAvoidtoner elasticity
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent identifies and optimizes the glass transition temperature parameter of the resin to a specific range of 50-90°C. This parameter optimization achieves the dual benefit of enabling low-temperature fixability while preserving sufficient toner elasticity, avoiding the problem of excessive adhesiveness that would occur with lower glass transition temperatures

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances the toner's releasability, prevents precipitation, and improves elasticity, resulting in better image quality and a wider fixing operation window, while reducing hot offset and maintaining high-temperature preservability and low-temperature fixability.

Implementation Method 1

The shell layer contains a first resin having a glass transition point of at least 50° C. and no greater than 90° C. The organic particles each contain a releasing agent and a second resin having a glass transition point of at least 90° C. and no greater than 110° C.

Methodology Applied
Scientific EffectGlass transition:

Data Source

PatentUS10001717B2Electrostatic latent image developing toner
Publication Date: 2018.06.19 KYOCERA DOCUMENT SOLUTIONS INC
  • US10001717B2 patent drawing
  • US10001717B2 patent drawing
  • US10001717B2 patent drawing

AI summary

An electrostatic latent image developing toner includes a plurality of toner particles each including a composite core and a shell layer covering a surface of the composite core. The composite core is a composite of a toner core and a plurality of organic particles each adhering to a surface of the toner core. The shell layer contains a first resin having a glass transition point of at least 50° C. and no greater than 90° C. The organic particles each contain a releasing agent and a second resin having a glass transition point of at least 90° C. and no greater than 110° C.