Toner with Low Modulus Convex Portions for Filming Suppression

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Solution Overview

Problem

Existing toners for developing electrostatic latent images face challenges with filming due to mechanical stress, which affects image quality and low temperature fixing performance, and struggle to maintain fluidity while suppressing filming.

Innovation Solution

A toner with a convex portion on its surface, where the convex portion is formed from a resin with a low Young's modulus, specifically a vinyl modified polyester resin, and has a controlled average length and covering percentage to reduce attachment to carriers and maintain low temperature fixing performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If a convex portion is formed on the toner surface to reduce filming, then filming is suppressed, but low temperature fixing performance deteriorates when using hard resin with high Young's modulus

Engineering Contradiction:
ImprovefilmingVSAvoidlow temperature fixing performance
Core Design Contradiction:
Object-generated harmful factorsVSTemperature

Solution Approach 1:

The invention changes the key parameter of Young's modulus from high to low (specifically ER(1)/ER(2) within 1.05 to 1.40). By using soft resin with low Young's modulus for the convex portion, the toner maintains its spherical shape and low temperature fixing performance while still suppressing filming through the convex structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite resin structure where the convex portion is made from resin (2) with low Young's modulus, different from the base resin (1). This composite approach allows the convex portion to provide filming suppression while the soft material composition maintains low temperature fixing performance.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If the covering percentage of convex portion is increased to suppress filming, then filming is reduced, but fluidity deteriorates

Engineering Contradiction:
ImprovefilmingVSAvoidfluidity
Core Design Contradiction:
Object-generated harmful factorsVSEase of operation

Solution Approach 1:

The invention optimizes the covering percentage parameter to within 30% to 70%, which is a specific range that balances filming suppression and fluidity maintenance. This parameter optimization ensures adequate convex portion coverage for filming prevention while leaving enough smooth surface area for good fluidity.

Inventive Principle:
Principle #35Parameter changes

3Strength

If styrene type resin is used for the convex portion to improve hardness, then mechanical strength is increased, but low temperature fixing performance deteriorates

Engineering Contradiction:
Improvemechanical strength of convex portionVSAvoidlow temperature fixing performance
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

The invention changes the material composition parameter by selecting resin (2) with low Young's modulus and appropriate glass transition temperature, specifically excluding styrene type resin. This material selection ensures the convex portion has sufficient mechanical strength while maintaining low temperature fixing performance through the soft resin composition.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS9377703B2Toner for developing electrostatic latent image and manufacturing method thereof
Publication Date: 2016.06.28 KONICA MINOLTA INC
  • US9377703B2 patent drawing
  • US9377703B2 patent drawing
  • US9377703B2 patent drawing

AI summary

According to one implementation, a toner includes a toner mother particle and a convex portion on a surface of the toner mother particle. The toner mother particle includes at least a resin (1). The convex portion is formed from a resin particle including at least a resin (2). An average value of a length of a long side of the convex portion is within a range of 0.1 to 0.5 μm. A ratio between a Young's modulus of a non-convex portion of the toner mother particle (ER (1)) and a Young's modulus of a convex portion of the toner mother particle (ER (2)) is a value (ER (1)/ER (2)) within the range of 1.2 to 2.0.