Toner Fixing with Ester Softening Agent for Odor and Transfer Control

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Solution Overview

Problem

Conventional image forming methods using organic solvents face issues with strong odor generation and toner transfer when another print medium is overlaid on a printed medium with a fixing solution applied, due to volatility and incomplete curing of toner images.

Innovation Solution

An image forming method and apparatus using toner particles with a binder resin containing a condensate of straight-chain diol and alkylene oxide adduct of bisphenol A, combined with an ester-based softening agent having a boiling point of at least 180°C, to soften and cure the binder resin effectively, preventing solvent volatilization and toner transfer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If an organic solvent with high volatility is used as the fixing solution, then the toner image can be formed, but a strong odor is generated

Engineering Contradiction:
Improvetoner image formationVSAvoidstrong odor
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the key parameter of the fixing solution from high volatility to low volatility organic solvents. This parameter change eliminates the strong odor problem while maintaining the toner image formation capability, as the low volatility prevents excessive evaporation and odor generation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the phase transition properties of low volatility organic solvents that remain in liquid state longer, allowing sufficient time for toner image formation without rapid evaporation. This controlled phase behavior prevents the strong odor associated with rapid vaporization of high volatility solvents.

Inventive Principle:
Principle #36Phase transitions

2Object-generated harmful factors

If an organic solvent with low volatility is used as the fixing solution, then the strong odor is suppressed, but the toner is hard to cure after being softened

Engineering Contradiction:
Improvestrong odor suppressionVSAvoidtoner curing
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent employs a composite toner structure containing both a binder resin and a curable component. The binder resin is softened by the low volatility organic solvent, while the curable component reacts to form a crosslinked structure, ensuring complete curing even with slower solvent evaporation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent incorporates a curable component in the toner that undergoes curing reaction after solvent application. This preliminary preparation of curable materials ensures that the toner will cure properly even when using low volatility solvents that take longer to evaporate, resolving the curing reliability issue.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If another print medium is overlaid on a print medium with applied fixing solution, then the printing process continues, but the softened toner transfers to the another print medium

Engineering Contradiction:
Improvecontinuous printingVSAvoidtoner image stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent prepares the toner with curable components before the fixing solution is applied. After the low volatility solvent softens the binder resin, the curable component undergoes a curing reaction that locks the toner image in place, preventing transfer to subsequent print media even during continuous printing operations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the chemical state of the toner from soft and transferable to cured and stable through a chemical reaction. This parameter change in the toner's molecular structure ensures image stability and prevents unwanted transfer when print media are overlaid during continuous printing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method suppresses strong odor generation and prevents toner transfer to another print medium, ensuring stable image formation and adhesion without thermal pressurization.

Implementation Method 1

applying, to the toner image, a fixing solution containing an ester-based softening agent having a boiling point of not less than 180° C. so as to fix the toner image to the print medium

Methodology Applied
Scientific EffectSoftening: Solvation

Implementation Method 2

toner particles having a binder resin which contains a condensate of straight-chain diol having 2 to 6 carbon atoms, an alkylene oxide adduct of bisphenol A and polyvalent carboxylic acid

Methodology Applied
Scientific EffectCuring: Chemical Bonding

Data Source

PatentUS11392051B2Image forming method, image forming device and set
Publication Date: 2022.07.19 BROTHER KOGYO KK
  • US11392051B2 patent drawing
  • US11392051B2 patent drawing

AI summary

An image forming method includes: forming a toner image on a print medium by using a toner including toner particles having a binder resin which contains a condensate of straight-chain diol having 2 to 6 carbon atoms, an alkylene oxide adduct of bisphenol A and polyvalent carboxylic acid; and applying, to the toner image, a fixing solution containing an ester-based softening agent having a boiling point of not less than 180° C. so as to fix the toner image to the print medium.