Toner Composition with Ionic Resin for Fogging Suppression

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing toners face challenges in suppressing image fogging across a broad back contrast range, especially under varying temperature and humidity conditions, leading to reduced image quality and increased toner consumption.

Innovation Solution

A toner composition incorporating a binder resin, a fatty acid metal salt with a polyvalent metal of valency 2 or higher, and a resin with an ionic functional group having a specific acid dissociation constant pKa range, which stabilizes charge distribution and improves pigment dispersion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If potential control devices are used to suppress fogging, then image quality is improved, but device complexity increases

Engineering Contradiction:
Improveimage qualityVSAvoiddevice complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent employs a toner formulation with charge control agents that provides fogging suppression without requiring complex potential control devices. The toner particles themselves contain the necessary charge control mechanisms, effectively making the toner a self-contained solution that eliminates the need for additional complex equipment.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the chemical parameters of the toner by incorporating specific charge control agents and resin combinations. This alters the charge characteristics of the toner particles, enabling fogging suppression through material composition rather than complex device control mechanisms.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If toner charge quantity is increased to prevent reverse polarity particles, then fogging is reduced, but image density and tinting strength may be compromised

Engineering Contradiction:
Improvefogging suppressionVSAvoidtoner consumption
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent optimizes the charge quantity parameter of toner particles by incorporating charge control agents. This creates a balanced charge distribution that prevents reverse polarity particles while maintaining appropriate image density and tinting strength, achieving fogging suppression without excessive toner consumption.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite toner particles containing multiple components including binder resin, charge control agents, and pigment. This composite structure allows the toner to achieve both sufficient charge for fogging prevention and appropriate optical properties for image quality.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If existing charge control agents are used, then charge quantity is improved, but rising performance of charge quantity deteriorates under high temperature and humidity conditions

Engineering Contradiction:
Improvecharge quantityVSAvoidcharge stability under environmental conditions
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent employs a composite charge control system combining multiple agents: a calixarene compound (first charge control agent) and an organoboron compound (second charge control agent). This composite approach provides both sufficient charge quantity and stable rising performance under high temperature and humidity conditions, overcoming the limitations of single-agent systems.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces specific chemical compounds as intermediaries that mediate the charging process. The calixarene and organoboron compounds act as intermediaries between the toner particles and the charging mechanism, providing stable charge control across varying environmental conditions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The toner effectively suppresses fogging across a wide back contrast range, maintaining image quality and reducing toner consumption, even under extreme environmental conditions, through sustained use.

Implementation Method 1

a resin having an ionic functional group which has an acid dissociation constant pKa of at least 6.0 and not more than 9.0

Methodology Applied
Scientific EffectElectrostatic interactions: Electrostatics

Implementation Method 2

a fatty acid metal salt of a polyvalent metal with valency of 2 or higher and a fatty acid with carbon atom number of at least 8 and not more than 28

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS9921501B2Toner and process for producing toner
Publication Date: 2018.03.20 CANON KK
  • US9921501B2 patent drawing
  • US9921501B2 patent drawing
  • US9921501B2 patent drawing

AI summary

A toner having a toner particle which contains a binder resin, a fatty acid metal salt, and a resin having an ionic functional group, in which the fatty acid metal salt is a fatty acid metal salt of a polyvalent metal with valency of 2 or higher and a fatty acid with carbon atom number of at least 8 and not more than 28, and the acid dissociation constant pKa of the resin having an ionic functional group is at least 6.0 and not more than 9.0.