Toner Particle Size Control for Aggregation Prevention

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Solution Overview

Problem

Electrostatic charge image development toners tend to aggregate in replenishment toner containers when the environment changes from high-temperature and high-humidity to low-temperature and low-humidity, leading to adhesion and condensation issues.

Innovation Solution

The use of negatively chargeable toner particles combined with layered-structure compound particles, where the volume-average particle diameter of the layered-structure compound particles is between 0.4 μm and 3.0 μm, and the ratio of their diameters to the toner particles is between 0.044 and 0.625, to prevent adhesion and aggregation by enhancing lubrication effects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If layered-structure compound particles with volume-average particle diameter Da < 0.4 μm or Da ≥ 3.0 μm or Da/Db ratio < 0.044 or Da/Db ratio > 0.625 are used, then the toner can be manufactured with conventional particle sizes, but the toner aggregates in replenishment toner containers when environment changes from high-temperature and high-humidity to low-temperature and low-humidity

Engineering Contradiction:
Improvetoner particle size controlVSAvoidtoner storage stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent optimizes the particle size parameters of layered-structure compound particles (Da: 0.4-3.0 μm) and their ratio to toner particles (Da/Db: 0.044-0.625) to prevent aggregation. This parameter optimization resolves the contradiction by finding the optimal size range that maintains both manufacturability and storage stability across temperature-humidity changes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite toner system combining toner particles with layered-structure compound particles (such as melamine cyanurate) in specific proportions. This composite structure provides both the manufacturability of conventional toner sizes and the aggregation-preventing properties of optimized layered-structure particles, resolving the reliability issue during storage.

Inventive Principle:
Principle #40Composite materials

2Reliability

If layered-structure compound particles with optimized Da (0.4-3.0 μm) and Da/Db ratio (0.044-0.625) are used, then toner aggregation is prevented in replenishment toner containers, but the device complexity increases due to precise particle size control requirements

Engineering Contradiction:
Improvetoner storage stabilityVSAvoidparticle size control system
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

By establishing specific parameter ranges (Da: 0.4-3.0 μm, Da/Db: 0.044-0.625), the patent simplifies the control process within these boundaries while ensuring aggregation prevention. The parameter optimization resolves the contradiction by defining clear manufacturing targets that maintain reliability without excessive complexity.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If conventional toner particles are used without optimized layered-structure compound particles, then the toner formulation is simpler, but adhesion and condensation issues occur in toner containers under environmental changes

Engineering Contradiction:
Improvetoner formulationVSAvoidadhesion and condensation
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The patent incorporates layered-structure compound particles (such as melamine cyanurate) as external additives in specific amounts (0.01-5 parts by weight per 100 parts by weight of toner particles). This composite formulation resolves the contradiction by adding minimal complexity to the toner system while effectively preventing adhesion and condensation under temperature-humidity changes.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The layered-structure compound particles act as intermediary substances between the toner particles and the container environment. These particles prevent direct adhesion and condensation by providing a protective interface, resolving the harmful effects while maintaining relatively simple toner formulation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Prevents toner adhesion and aggregation in toner containers across varying environmental conditions, ensuring consistent toner supply and performance in image forming apparatuses.

Implementation Method 1

The layered-structure compound particles have a volume-average particle diameter Da of 0.4 μm or more and less than 3.0 μm, and a ratio Da/Db of the volume-average particle diameter Da of the layered-structure compound particles to a volume-average particle diameter Db of the toner particles is 0.044 or more and 0.625 or less, thereby making it unlikely to aggregate in a replenishment toner container

Methodology Applied
Scientific EffectLubrication: Lubrication

Data Source

PatentUS11106148B2Electrostatic charge image development toner, electrostatic charge image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method
Publication Date: 2021.08.31 FUJIFILM BUSINESS INNOVATION CORP
  • US11106148B2 patent drawing
  • US11106148B2 patent drawing
  • US11106148B2 patent drawing

AI summary

An electrostatic charge image development toner that is negatively chargeable contains toner particles and layered-structure compound particles. The layered-structure compound particles have a volume-average particle diameter Da of 0.4 μm or more and less than 3.0 μm. The ratio Da/Db of the volume-average particle diameter Da of the layered-structure compound particles to the volume-average particle diameter Db of the toner particles is 0.044 or more and 0.625 or less.