Toner Formulation with Low Pigment Concentration for High Density

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Solution Overview

Problem

Conventional toners for electrographic color image forming require high pigment concentrations to achieve sufficient image density, leading to increased costs and decreased image sharpness, while also resulting in high toner adhesion amounts that contribute to environmental issues and inadequate color reproduction ranges.

Innovation Solution

A toner formulation with a pigment concentration of 3.0% to 8.5% by mass and a volume average particle diameter of 2.0 to 6.0 μm, containing a binder resin and a pigment dispersant, which achieves a reflection density of 1.2 to 2.5 with a low toner adhesion amount of 0.25 mg/cm², reducing consumption rates and environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If pigment concentration is increased to achieve sufficient image density, then image density is improved, but toner cost increases and image sharpness decreases

Engineering Contradiction:
Improveimage densityVSAvoidpigment concentration
Core Design Contradiction:
Measurement precisionVSQuantity of substance

Solution Approach 1:

The patent changes the particle size parameter of the toner to 5.1 μm or less, which fundamentally alters how pigment is distributed and utilized in the toner layer. This parameter change enables achieving sufficient image density (ID≥1.2) with reduced pigment concentration (3-11% by mass), resolving the contradiction between image density and pigment quantity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite toner material system consisting of binder resin, pigment, and specific additives in optimized proportions. This composite structure with controlled particle size and composition enables efficient light absorption and image density achievement without requiring high pigment concentrations, thus resolving the contradiction.

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If pigment concentration is increased to achieve sufficient image density, then image density is improved, but toner cost increases

Engineering Contradiction:
Improveimage densityVSAvoidtoner cost
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

By changing the critical parameter of particle size to 5.1 μm or less, the patent enables cost-effective toner formulation with reduced pigment content (3-11% by mass). This parameter change fundamentally alters the cost structure while maintaining sufficient image density, resolving the contradiction between image density and manufacturing cost.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If toner particle size is reduced to improve image resolution, then image sharpness is improved, but image density decreases

Engineering Contradiction:
Improveimage sharpnessVSAvoidimage density
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The patent optimizes the particle size parameter to a specific range (5.1 μm or less, preferably 4.0-5.1 μm) that simultaneously achieves both high image sharpness and sufficient image density. This precise parameter optimization resolves the contradiction between image sharpness and image density that plagues conventional toners.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If toner adhesion amount is reduced to decrease environmental impact, then environmental friendliness is improved, but image density decreases

Engineering Contradiction:
Improveenvironmental impactVSAvoidimage density
Core Design Contradiction:
Object-affected harmful factorsVSMeasurement precision

Solution Approach 1:

By changing the particle size parameter to 5.1 μm or less, the patent enables achieving sufficient image density (ID≥1.2) with dramatically reduced toner adhesion amounts (0.2-0.4 mg/cm²). This parameter change resolves the contradiction between environmental friendliness and image density, allowing low-toner formulations to achieve offset-printing quality images.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The toner achieves high-quality images with reduced pigment usage, lower toner consumption, and enhanced color reproduction ranges, comparable to offset printing quality, while minimizing environmental impact and costs.

Implementation Method 1

developing the latent electrostatic image using a toner to form a visible image

Methodology Applied
Scientific EffectElectrostatic deposition: Electrostatic Deposition

Data Source

PatentUS8932788B2Toner, developer, and image forming method
Publication Date: 2015.01.13 RICOH CO LTD
  • US8932788B2 patent drawing
  • US8932788B2 patent drawing
  • US8932788B2 patent drawing

AI summary

The present invention provides a toner containing at least a binder resin and a pigment, wherein the amount of the pigment in the toner is 3.0% by mass to 8.5% by mass, the volume average particle diameter of the toner is 2.0 μm to 6.0 μm, and a monochrome image, which has been fixed on a recording medium so that the amount of the toner adhered onto the recording medium is 0.25 mg/cm2, has a reflection density of 1.2 to 2.5.