Toner Particle Size Control for High-Resolution Imaging

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional toners with large particle diameters fail to produce high-quality images with fine details, leading to issues like poor thin-line reproducibility, blurring, and increased gloss, while those with small particle diameters suffer from residual-image phenomena, fouling, and reduced toner transfer efficiency.

Innovation Solution

A toner with a volume-median diameter of 4.0 to 7.5 μm, high average circularity, and a controlled particle distribution, incorporating a charge control agent with a specific dispersal, and a narrow particle size distribution to enhance electrification and transferability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional toners with large particle diameter are used, then productivity and ease of manufacture are maintained, but image quality deteriorates with poor thin-line reproducibility and blurring

Engineering Contradiction:
Improvethin-line reproducibilityVSAvoidparticle diameter
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The patent applies parameter changes by precisely controlling the particle diameter of toner particles to fall within the range of 3.0 μm to 6.0 μm, with a volume-average particle diameter of 4.0 μm to 6.0 μm. This specific parameter range resolves the contradiction by enabling high-resolution image formation with thin lines while avoiding the blurring associated with larger particles, thus improving manufacturing precision without requiring a fundamental change in the toner system.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If toner particle diameter is reduced to improve image quality, then thin-line reproducibility improves, but residual-image phenomenon and fouling increase

Engineering Contradiction:
Improveline clearnessVSAvoidresidual-image phenomenon
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent resolves this contradiction by implementing a dual-parameter control strategy: (1) controlling the particle diameter within 3.0 μm to 6.0 μm to ensure clear line reproduction, and (2) limiting the population number percentage of particles with diameter ≤3.56 μm to 6% or less to prevent residual-image phenomenon and fouling. This combination of parameters achieves both high line clearness and eliminates harmful residual effects.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining toner particles with specific size distribution characteristics. The toner consists of particles in the 3.0-6.0 μm range with controlled distribution, creating a composite structure that balances the need for fine line reproduction with the need to avoid excessive fine particles that cause residual imaging and fouling.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If toner particle diameter is reduced to increase resolution, then dot size decreases, but toner transfer efficiency and electrification deteriorate

Engineering Contradiction:
ImproveresolutionVSAvoidtoner transfer efficiency
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent resolves this contradiction through optimized parameter selection: the particle diameter range of 3.0 μm to 6.0 μm provides sufficiently small dot sizes for high resolution (achieving 300 dpi or higher), while the volume-average diameter of 4.0 μm to 6.0 μm ensures adequate mass and charge for reliable transfer. The controlled particle distribution further ensures that not too many particles are at the lower size limit, maintaining electrification and transfer efficiency.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If toner contains high proportion of fine particles to improve resolution, then dot density increases, but image stability and cleaning performance deteriorate

Engineering Contradiction:
Improvedot densityVSAvoidimage stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent resolves this contradiction by implementing precise control over the particle size distribution parameters. The population number percentage of particles with diameter ≤3.56 μm is limited to 6% or less, which prevents excessive fine particle content that would cause instability and cleaning difficulties. Simultaneously, the overall particle diameter range of 3.0-6.0 μm with volume-average of 4.0-6.0 μm ensures sufficient dot density for high resolution, achieving a balanced composition that is both high-resolution and stable.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The toner achieves improved image quality, reduced gloss, and stable cleaning performance, preventing fouling and residual-image issues, while maintaining high-resolution image stability and transfer efficiency.

Implementation Method 1

the ability to be instantaneously charged by friction

Methodology Applied
Scientific EffectTriboelectric effect: Triboelectric Effect

Implementation Method 2

electrostatic-image development

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Data Source

PatentUS8871413B2Toners for electrostatic-image development, cartridge employing toner for electrostatic-image development, and image-forming apparatus
Publication Date: 2014.10.28 MITSUBISHI CHEM CORP
  • US8871413B2 patent drawing
  • US8871413B2 patent drawing
  • US8871413B2 patent drawing

AI summary

An object of the invention is to provide a toner which is effective in improving image quality while inhibiting white-background fouling, residual-image phenomenon (ghost), blurring (suitability for solid printing), and the like that occur depending on the proportion of a fine powder having a particle diameter not larger than a specific value, and which has satisfactory removability in cleaning, mitigates problems concerning fouling, etc. in long-term use even on a high-speed printer, and attains excellent image stability. Another object is to provide an image-forming apparatus and a toner cartridge each employing the toner. The invention provides a toner for electrostatic-image development satisfying all of the following (1) to (4) or a toner for electrostatic-image development which is a toner containing a charge control agent and satisfying all of the following (5) to (7). The invention further provides an image-forming apparatus and a toner cartridge each employing the toner.(1) To have a volume-median diameter (Dv50) of from 4.0 μm to 7.5 μm.(2) To have an average degree of circularity of 0.93 or higher.(3) A volume-median diameter (Dv50) of the toner and population number % of toner particles having a particle diameter of from 2.00 μm to 3.56 μm (Dns) in the toner satisfy the relationship Dns≦0.233 EXP(17.3/Dv50).(4) To have a coefficient of variation in number of 24.0% or lower.(5) To have a volume-median diameter (Dv50) of from 4.0 μm to 7.5 μm.(6) A volume-median diameter (Dv50) of the toner and population number % of toner particles having a particle diameter of from 2.00 μm to 3.56 μm (Dns) in the toner satisfy the relationship Dns≦0.233 EXP(17.3/Dv50).(7) When the charge control agent on the toner surface is cleaned, the resultant depressions have an average diameter of 500 nm or smaller.