Toner Production pH Control to Suppress Aluminum Hydroxide Gel

Solution Overview

Problem

Existing methods for producing toners for electrostatic charge images face issues with color spots and fogging due to the formation of gel-like substances, particularly aluminum hydroxide, which are difficult to remove and affect image quality.

Innovation Solution

A method involving the aggregation of resin particles using an aluminum aggregating agent, followed by heating and fusing, cooling, and adjusting the pH of the toner particle dispersion to between 8 and 11 to prevent gel-like substance formation and maintain chargeability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If an aluminum aggregating agent is used to aggregate resin particles, then aggregation efficiency is improved, but gel-like substances (aluminum hydroxide) are formed causing color spots and fogging

Engineering Contradiction:
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes the harmful aluminum hydroxide gel-like substances from the system through washing steps. The toner particles are washed with water to remove aluminum hydroxide formed during aggregation, thereby eliminating the cause of color spots and fogging while maintaining the benefits of aluminum-based aggregation

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces an intermediary washing step between aggregation and toner formation. This washing step acts as a mediator that removes harmful aluminum hydroxide while preserving the aggregated toner particle structure, allowing the use of aluminum aggregating agents without their harmful side effects

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-generated harmful factors

If pH is adjusted to less than 8 to remove aluminum hydroxide, then color spots are suppressed, but chargeability deteriorates

Engineering Contradiction:
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent performs preliminary removal of aluminum hydroxide through washing before pH adjustment is needed. By removing aluminum hydroxide in advance through washing steps, the patent avoids the need to adjust pH to less than 8, thereby maintaining chargeability while still suppressing color spots

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent cushions against the potential problem of color spots by preemptively removing aluminum hydroxide through washing. This prior removal prevents the formation of color spots without requiring extreme pH adjustment that would harm chargeability, thus cushioning against both problems simultaneously

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Object-generated harmful factors

If washing is performed to remove aluminum hydroxide, then image quality is improved, but production complexity increases

Engineering Contradiction:
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent merges the washing step with existing process stages. The washing is integrated into the toner production flow, combining particle separation, washing, and drying into a unified process rather than adding completely separate equipment, thereby reducing overall complexity while still removing aluminum hydroxide effectively

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively suppresses the occurrence of color spots and fogging in the final image by preventing the formation of aluminum hydroxide and maintaining optimal charge properties.

Implementation Method 1

an aggregation step of aggregating at least resin particles contained in a dispersion by using an aluminum aggregating agent to form aggregated particles

Methodology Applied
Scientific EffectCoagulation: Coagulation

Implementation Method 2

a fusing step of heating and fusing the aggregated particles to form fused particles

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

a cooling step of cooling a dispersion containing the fused particles to obtain a toner particle dispersion

Methodology Applied
Scientific EffectFreezing: Freezing

Data Source

PatentUS20220308482A1Method for producing toner for developing electrostatic charge image, and toner for developing electrostatic charge image
Publication Date: 2022.09.29
  • US20220308482A1 patent drawing
  • US20220308482A1 patent drawing

AI summary

A method for producing a toner for developing an electrostatic charge image includes: aggregating at least resin particles contained in a dispersion by using an aluminum aggregating agent to form aggregated particles; heating and fusing the aggregated particles to form fused particles; cooling a dispersion containing the fused particles to obtain a toner particle dispersion; and adjusting a pH of the toner particle dispersion to 8 or more and 11 or less.