Toner Composition Reactive Coalescing Agent

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Solution Overview

Problem

Existing toner production methods using triboelectricity for charging result in nonuniform charge distribution and instability, making it difficult to control and maintain the charging of small toner particles, which affects print quality and reliability.

Innovation Solution

A method involving the use of a latex, an aqueous colorant dispersion, and an optional wax dispersion to form a blend, followed by heating below the glass transition temperature, adding a reactive coalescing agent like glycol esters of vegetable oil fatty acids to coalesce toner particles, resulting in core-shell toner particles with uniform size and charging characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If triboelectric charging is used to charge toner particles, then the toner can be moved and developed via electric fields, but the charge distribution becomes nonuniform and unstable, especially for small particles

Engineering Contradiction:
Improvecharging stabilityVSAvoidcharge distribution uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent introduces a liquid carrier as an intermediary medium to transfer charge uniformly to toner particles. Instead of direct triboelectric charging which causes nonuniform charge distribution, the liquid carrier acts as a mediator that distributes charge evenly across the toner particles through its fluid properties and contact mechanisms, thereby improving charge uniformity while maintaining charging stability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the charging mechanism from solid-to-solid triboelectric contact to liquid-mediated charging. By changing the physical state and charging parameters from direct particle-to-particle or particle-to-carrier contact to liquid carrier-mediated charge transfer, the system achieves more uniform and stable charge distribution on toner particles

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If small toner particles (about 5 micron diameter) are used to achieve offset print quality, then print quality improves, but long-term stability and reliability decrease

Engineering Contradiction:
Improveprint qualityVSAvoidsystem stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The liquid carrier serves as a stabilizing intermediary for small toner particles. It provides a consistent charging environment that compensates for the inherent instability of small particles, ensuring reliable charge distribution and maintaining system stability while enabling the use of small 5-micron particles for high-quality offset printing

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If triboelectric charging is used, then charging can be achieved, but the charging becomes unpredictable due to material sensitivity

Engineering Contradiction:
Improvecharging capabilityVSAvoidcharging predictability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The liquid carrier acts as a buffering intermediary that decouples the charging process from direct material-to-material contact. This intermediary layer reduces sensitivity to material variations and environmental conditions, making the charging process more predictable and controllable while maintaining ease of manufacture

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process produces toner particles with a narrow size distribution, optimal surface area, and robust triboelectric charging, reducing production time and manufacturing costs while improving print quality and stability.

Implementation Method 1

heating the blend at a temperature below the glass transition temperature of the latex to form aggregated toner particles

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 2

adding a reactive coalescing agent to the toner particles thereby coalescing the toner particles

Methodology Applied
Scientific EffectCoalescence:

Implementation Method 3

Placing charge on the particles, to enable movement and development of images via electric fields, is most often accomplished with triboelectricity

Methodology Applied
Scientific EffectTriboelectricity: Triboelectric Effect

Data Source

PatentUS7943283B2Toner compositions
Publication Date: 2011.05.17 XEROX CORP
  • US7943283B2 patent drawing
  • US7943283B2 patent drawing
  • US7943283B2 patent drawing

AI summary

Processes for producing toner are provided which utilize reactive coalescing agents in forming the toner particles, as well as toners produced by such processes.