Toner Production via Segmented Charge Control Resin

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Solution Overview

Problem

Existing toner production methods face challenges in achieving excellent triboelectric chargeability and high-temperature offset resistance, particularly when using negatively chargeable charge control resins that do not soften at 180°C, as they tend to have poor dispersibility and viscoelastic properties, leading to reduced triboelectric charges and offset resistance.

Innovation Solution

A method involving the pulverization of negatively chargeable charge control resins to an average particle size of 0.05 to 2 μm, followed by melt-kneading with a resin binder and colorant, and subsequent classification to enhance dispersibility and triboelectric properties, thereby improving triboelectric chargeability and high-temperature offset resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If negatively chargeable charge control resins that do not soften at 180°C or lower are used, then high-temperature offset resistance is improved, but dispersibility deteriorates leading to poor triboelectric chargeability

Engineering Contradiction:
Improveoffset resistance temperatureVSAvoiddispersibility
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The charge control resin is divided into fine particles with an average particle size of 0.05 to 2 μm through pulverization. This segmentation allows the resin to disperse more uniformly in the toner composition while maintaining its high softening point, thereby achieving both good dispersibility and high-temperature offset resistance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The particle size parameter of the charge control resin is changed from larger conventional sizes to the specific range of 0.05 to 2 μm. This parameter change improves dispersibility without altering the chemical composition or softening point, resolving the contradiction between temperature resistance and dispersibility

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If charge control resin particle size is reduced to improve dispersibility, then triboelectric chargeability is improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovedispersibilityVSAvoidpulverization process complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The charge control resin is pulverized to the desired particle size before being mixed with other toner components. This preliminary action ensures uniform dispersibility in the final product while using a simple pulverization process that does not require complex manufacturing equipment

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a toner with enhanced triboelectric chargeability and high-temperature offset resistance by ensuring better dispersibility of the charge control resin within the resin binder, maintaining viscoelastic properties, and improving the overall performance of the toner.

Implementation Method 1

melt-kneading at least a pulverized product of the negatively chargeable charge control resin obtained in the step (A), a resin binder, and a colorant

Methodology Applied
Scientific EffectMelt-kneading:

Implementation Method 2

pulverizing a negatively chargeable charge control resin that does not soften at a temperature of 180° C. or lower to an average particle size of from 0.05 to 2 μm

Methodology Applied
Scientific EffectPulverization: Abrasion

Implementation Method 3

negatively chargeable charge control resin... giving electric charges to toners... excellent triboelectric chargeability

Methodology Applied
Scientific EffectTriboelectric chargeability: Triboelectric Effect

Data Source

PatentUS7820353B2Method for producing toner
Publication Date: 2010.10.26 KAO CORP
  • US7820353B2 patent drawing
  • US7820353B2 patent drawing
  • US7820353B2 patent drawing

AI summary

A method for producing a toner, including at least the following steps: step (A): pulverizing a negatively chargeable charge control resin that does not soften at a temperature of 180° C. or lower to an average particle size of from 0.05 to 2 μm; step (B): melt-kneading at least a pulverized product of the negatively chargeable charge control resin obtained in the step (A), a resin binder, and a colorant; and step (C): pulverizing a melt-kneaded product obtained in the step (B) and classifying the pulverized product. The toner obtained according to the present invention is suitably used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.