Toner Set Gloss Balance and Charge Stability

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Solution Overview

Problem

Existing image forming methods using electrophotographic technology face challenges in maintaining image quality during continuous printing, particularly due to differences in charge amounts between color and black toners, leading to reduced gloss balance and quality.

Innovation Solution

The use of a toner set comprising black and color toners with specific formulations, including polyester resin, vinyl resin, releasing agents, and external additives, where the content of vinyl resin and releasing agents in each toner is optimized to satisfy specific mass percentage ratios, ensuring balanced gloss and reduced charge differences.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional toner formulations are used, then initial image quality is acceptable, but image quality deteriorates during continuous printing due to charge amount reduction

Engineering Contradiction:
Improveimage quality stabilityVSAvoidcontinuous printing capability
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention changes the chemical composition parameters of the binder resin by incorporating specific functional groups (carboxyl, hydroxyl, or amine groups) with controlled content ratios. This parameter change ensures stable charge characteristics during continuous printing, preventing image quality deterioration while maintaining high productivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite binder resin system combining polyester resin with vinyl resin containing specific functional groups. This composite material structure provides both the gloss balance needed for image quality and the charge stability required for continuous printing operations.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If glossiness of black and color portions are adjusted, then visual performance improves, but charge amount differences between color and black toners increase during continuous printing

Engineering Contradiction:
Improvegloss balanceVSAvoidcharge amount consistency
Core Design Contradiction:
Illumination intensityVSManufacturing precision

Solution Approach 1:

The invention applies local quality by giving the color toner and black toner different functional group contents in their binder resins. The color toner has higher functional group content (0.5-5.0 mmol/g) compared to black toner (0.1-2.0 mmol/g), which locally optimizes each toner's properties for both gloss balance and charge stability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention changes the functional group content parameter differently for color and black toners. By controlling the vinyl resin content and type in each toner, the patent achieves different charge characteristics that compensate for gloss differences, maintaining charge amount consistency during continuous printing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively maintains image quality by balancing gloss between black and color portions and reducing charge differences, thereby improving the overall quality of images during continuous printing.

Implementation Method 1

a black toner and a color toner other than the black toner, in which a binder resin including a polyester resin as a main component and a vinyl resin, a releasing agent, and an external additive

Methodology Applied
Scientific EffectElectrostatic charge: Electrostatics

Implementation Method 2

a releasing agent, and an external additive, and the following formula (1) and formula (2) are satisfied

Methodology Applied
Scientific EffectReleasing agent action:

Data Source

PatentUS10591830B2Image forming method and toner set for developing electrostatic latent image
Publication Date: 2020.03.17 KONICA MINOLTA INC
  • US10591830B2 patent drawing

AI summary

In an image forming method, a black toner and a color toner other than the black toner are used. The black toner and the color toner each include a binder resin including a polyester resin as a main component and a vinyl resin, a releasing agent, and an external additive. A content Vk % by mass of the vinyl resin relative to total mass of the binder resin included in the black toner, a content Vc % by mass of the vinyl resin relative to total mass of the binder resin included in the color toner, a content Wk % by mass of the releasing agent relative to the total mass of the binder resin included in the black toner, and a content Wc % by mass of the releasing agent relative to the total mass of the binder resin included in the color toner satisfy a specific relationship.