Toner Shell Layer Structure for Fine Line Reproducibility

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Solution Overview

Problem

Existing electrostatic charge image developing toners face challenges in achieving good electrical characteristics and fine line reproducibility when using large-diameter particles, such as scaly pigments and light-emitting particles, due to difficulties in obtaining complete resin layer coverage and preventing particle aggregation.

Innovation Solution

The development of an electrostatic charge image developing toner with a core particle having a large-diameter particle and a shell layer composed of at least two resin layers, where the outermost layer is an amorphous resin, to enhance resin layer adhesion and prevent particle aggregation, thereby improving fine line reproducibility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If large-diameter particles such as scaly pigments and light-emitting particles are used as color material, then special color effects can be achieved, but it becomes difficult to obtain good electrical characteristics and powder fluidity

Engineering Contradiction:
Improvespecial color effectsVSAvoidelectrical characteristics
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent uses a composite resin layer structure combining amorphous resin and releasing agent in specific layers. The amorphous resin provides adhesion to large-diameter particles while the releasing agent enables proper release from the drum, achieving both special color effects and reliable electrical characteristics through material composition optimization.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies different resin properties to different layers: the amorphous resin is placed in layers requiring strong adhesion to large-diameter particles, while releasing agents are placed in layers requiring release functionality. This local differentiation of material properties resolves the contradiction between maintaining electrical characteristics and achieving special color effects.

Inventive Principle:
Principle #3Local quality

2Adaptability or versatility

If large-diameter particles such as scaly pigments and light-emitting particles are used as color material, then special color effects can be achieved, but it becomes difficult to obtain good powder fluidity

Engineering Contradiction:
Improvespecial color effectsVSAvoidpowder fluidity
Core Design Contradiction:
Adaptability or versatilityVSEase of operation

Solution Approach 1:

The composite resin layer structure with amorphous resin and releasing agent creates optimal surface properties that prevent particle aggregation while maintaining powder fluidity. The releasing agent components specifically address fluidity issues by reducing inter-particle friction and improving flow characteristics.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition parameters of the resin layers by incorporating amorphous resin with specific molecular structure and releasing agents with low melting points. These parameter changes reduce particle aggregation and improve powder fluidity while maintaining special color effects.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If a shell layer is composed of only one resin layer or includes at least two resin layers with releasing agent in the outermost layer, then releasing function is improved, but fine line reproducibility deteriorates

Engineering Contradiction:
Improvereleasing functionVSAvoidfine line reproducibility
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent segments the shell layer into multiple layers with amorphous resin and releasing agents arranged in specific sequences. This segmentation allows each layer to perform its specific function: amorphous resin layers provide adhesion and fine line definition, while releasing agent layers provide release functionality, resolving the contradiction between releasing function and fine line reproducibility.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different resin qualities to different layers: amorphous resin with high adhesion is placed in layers requiring fine line definition, while releasing agents are placed in outer layers requiring release functionality. This local quality differentiation enables both fine line reproducibility and proper releasing function.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS12197169B2Electrostatic charge image developing toner, method for producing electrostatic charge image developing toner, electrostatic charge image developer, toner cartridge, process cartridge, and image forming apparatus
Publication Date: 2025.01.14 FUJIFILM BUSINESS INNOVATION CORP
  • US12197169B2 patent drawing
  • US12197169B2 patent drawing

AI summary

An electrostatic charge image developing toner includes a toner particle, and the toner particle includes: a core particle containing a large-diameter particle having a number average particle diameter of 1 μm or more; and a shell layer that includes at least two resin layers each containing an amorphous resin and covers a surface of the core particles, and an outermost layer of the at least two resin layers is a resin layer being made of the amorphous resin.