Toner Manufacturing via Silicon Condensation

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Solution Overview

Problem

Existing toners face issues with fine particle release during prolonged printing, affecting transferability and adhesiveness, as well as reduced flowability and thermal resistance due to the detachment of fine particles from the toner surface.

Innovation Solution

A method of manufacturing toners involving a silicon compound represented by Formula (1) is used to create a mixed solution with fine particles and toner base particles, adjusting the pH to 7.0 or more and 12.0 or less to condense the silicon compound, ensuring the fine particles are firmly fixed to the toner surface, reducing their release and enhancing adhesiveness and transferability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If resin fine particles are embedded on the surface of toner particles to improve thermal resistance, then thermal resistance is improved, but transferability may be deteriorated and fine particles are released during prolonged printing

Engineering Contradiction:
Improvethermal resistanceVSAvoidtransferability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent uses a composite structure consisting of toner base particles with resin fine particles embedded on the surface, forming a multi-component system that combines the thermal resistance benefits of resin particles with the transferability advantages of the toner base material

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The resin fine particles are selectively embedded on the surface of the toner particles rather than throughout the entire particle, providing localized thermal resistance enhancement while maintaining the overall transferability characteristics of the toner base particles

Inventive Principle:
Principle #3Local quality

2Object-generated harmful factors

If inorganic fine particles are added to decrease adhesiveness, then adhesiveness is reduced, but fine particles are difficult to attach to convex portions and adhesiveness is not sufficiently decreased

Engineering Contradiction:
ImproveadhesivenessVSAvoidparticle attachment
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent uses an aqueous slurry as an intermediary medium to facilitate the attachment of inorganic fine particles to the toner particle surface, enabling uniform distribution and effective attachment that directly addresses the adhesiveness issue

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If organic fine particles are attached on the surface of toner base particles to improve adhesion, then adhesion to developing sleeve is improved, but image concentration is reduced after printing large number of sheets due to particle embedding

Engineering Contradiction:
ImproveadhesionVSAvoidimage concentration
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent optimizes the particle size parameters of the inorganic fine particles (3 nm to 500 nm) and controls their concentration in the aqueous slurry to achieve the right balance between adhesion improvement and maintaining image concentration during prolonged printing

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively prevents fine particle release and improves toner adhesiveness and transferability, maintaining printing quality even after printing a large number of sheets by firmly embedding the fine particles within the toner base particles.

Implementation Method 1

adjusting a pH of the mixed solution to 7.0 or more and 12.0 or less to condense the silicon compound

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

the fine particles are firmly fixed to the surface of the toner base particles

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

preparing a mixed solution including the following components i) a silicon compound represented by Formula (1)... in an aqueous medium

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS10345726B2Method of manufacturing toner
Publication Date: 2019.07.09 CANON KK
  • US10345726B2 patent drawing
  • US10345726B2 patent drawing
  • US10345726B2 patent drawing

AI summary

There is provided a method of manufacturing a toner including a toner particle containing a binder resin, the method including:process 1: preparing a mixed solution including the following components i) to iii) in an aqueous medium:i) a particular silicon compound,ii) a fine particle having a number average particle diameter of 3 nm or more and 500 nm or less, andiii) a toner base particle containing the binder resin; andprocess 2: adjusting a pH of the mixed solution to 7.0 or more and 12.0 or less to condense the silicon compound,wherein the fine particle has an absolute value of zeta potential of 10.0 mV or more at the pH of the mixed solution of process 1.