Toner Surface Additive Package for SCD Charging

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Solution Overview

Problem

Single Component Development (SCD) toner systems face issues with low charge and broad charge distribution, high fines content, toner robustness, and print defects such as ghosting and low toner density, particularly in high-speed printing and extreme environments.

Innovation Solution

A novel toner composition incorporating a surface additive package comprising hexamethyldisilazane (HMDS) surface-treated silica, sol-gel silica, polydimethylsiloxane (PDMS) surface-treated silica, and an organic spacer comprising melamine and polymethylmethacrylate (PMMA), which enhances charging and flow characteristics, reducing print defects and drum contamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If triboelectric charging is used in SCD systems by rubbing toner between blade and donor roll, then toner can be charged for image development, but the time for toner to flow through the gap is very short causing low charge and broad charge distribution

Engineering Contradiction:
Improvecharge uniformityVSAvoidtoner flow time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent modifies the surface properties of toner particles by incorporating specific surface additives (silica, PDMS, HMDS) that change the triboelectric charging characteristics. This allows for more uniform charge distribution within the short residence time between blade and donor roll, addressing the fundamental limitation of SCD systems without requiring longer flow time.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If non-magnetic toner is used in SCD systems to enable sharp color images, then image quality improves, but toner robustness in aging and extreme environments deteriorates

Engineering Contradiction:
Improveimage sharpnessVSAvoidtoner robustness
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent creates a composite toner formulation combining non-magnetic materials for image sharpness with a carefully selected mix of surface additives (silica, PDMS, HMDS) that provide environmental stability and robustness. This composite approach allows the toner to maintain both image quality and reliability under aging and extreme conditions.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If high fines content is present in SCD toner, then more toner particles are available for charging, but charge distribution becomes broader and print background deteriorates

Engineering Contradiction:
Improvetoner particle availabilityVSAvoidprint background quality
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent changes the surface parameters of toner particles through the addition of specific surface additives that modify charging characteristics. This allows high fines content toner to achieve narrower charge distribution and better print background quality by improving the uniformity of charge acquisition across particles of varying sizes.

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If toner is charged through charging/metering blade in SCD systems, then toner can be supplied to development roll, but high stress under blade causes toner to stick reducing charge and flowability

Engineering Contradiction:
Improvetoner supplyVSAvoidtoner flowability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent modifies the surface parameters of toner particles with specific surface additives (particularly PDMS and silica) that reduce adhesion to the charging blade while maintaining adequate triboelectric charging. This parameter change allows toner to flow smoothly through the high-stress blade region without sticking, preserving both charge and flowability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel toner composition achieves high print quality with improved charging, flow, and reduced drum contamination, suitable for high-speed printing and extreme environments, while minimizing defects like ghosting and white bands.

Implementation Method 1

Placing charge on the particles, to enable movement and development of images via electric fields, is often accomplished with triboelectricity. Triboelectric charging may occur either by mixing the toner with larger carrier beads in a TCD system, or by rubbing the toner between a blade and donor roll in an SCD system.

Methodology Applied
Scientific EffectTriboelectric charging: Triboelectric Effect

Implementation Method 2

a surface additive package comprising hexamethyldisilazane (HMDS) surface-treated silica, sol-gel silica, polydimethylsiloxane (PDMS) surface-treated silica

Methodology Applied
Scientific EffectSurface treatment: Adsorption

Data Source

PatentUS9164410B2Toner compositions for single component development system
Publication Date: 2015.10.20 XEROX CORP
  • US9164410B2 patent drawing
  • US9164410B2 patent drawing
  • US9164410B2 patent drawing

AI summary

A toner composition with a novel surface additive package for developing images is provided. The additive package comprises a sol-gel silica, a PDMS silica, an HMDS silica, and an organic spacer such as PMMA, and melamine. The toner composition exhibits improved properties and are useful for high speed printing on Single Component Development systems.