Toothpaste Formulation with Polymers for Enamel Protection

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Solution Overview

Problem

Current tooth cleaning products often cause micro-injuries to the gums and oral mucosa due to mechanical stress and chemical stimuli, leading to irritation and potential bleeding, while also risking damage to the tooth enamel with their abrasive nature, and they fail to effectively revitalize and strengthen these tissues for quick regeneration.

Innovation Solution

A tooth cleaning and care product formulation containing calcium glycerophosphate, carboxymethyl cellulose, xanthan gum, cocamidopropyl betaine, and optionally vitamin E, which forms a microfine layer on tooth enamel, reduces surface roughness, enhances active ingredient deposition, and creates a stable foam to minimize abrasiveness and promote gum and mucosa vitality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If polishing agents with certain abrasiveness are used to achieve cleaning performance, then cleaning effectiveness is improved, but tooth enamel and dentin may be damaged

Engineering Contradiction:
Improvecleaning performanceVSAvoiddamage to tooth surface
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the physical-chemical parameters of the abrasive particles by using polymers with specific molecular weights and compositions (carboxymethyl cellulose with degree of substitution 0.5-2.5 and xanthan gum with specific viscosity ranges) to create a gentler abrasion mechanism that maintains cleaning effectiveness while reducing damage to tooth enamel and dentin

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite formulation combining multiple polymers (carboxymethyl cellulose and xanthan gum) with surfactants (cocamidopropyl betaine) to create a synergistic system where the polymer composite provides gentle mechanical action while the surfactant complex reduces surface tension and enhances cleaning without increasing abrasiveness

Inventive Principle:
Principle #40Composite materials

2Productivity

If mechanical stress is applied during tooth cleaning to remove plaque, then cleaning effectiveness is improved, but micro-injuries to gums and oral mucosa are caused

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidmicro-injuries to gums
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the rheological parameters of the toothpaste by incorporating polymers with specific viscosity characteristics (xanthan gum with viscosity ≥1200 mPa·s at 1% concentration) to create a softer, more compliant paste that adapts to gum contours and reduces mechanical trauma during brushing while maintaining plaque removal capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces surfactants (cocamidopropyl betaine) as intermediary substances that reduce the interfacial tension between the toothpaste and oral tissues, allowing for effective plaque removal with reduced mechanical stress on the gums and oral mucosa

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If surfactants are used to enhance cleaning and foaming, then cleaning performance is improved, but the oral mucosa becomes more sensitive to chemical stimuli

Engineering Contradiction:
Improvecleaning performanceVSAvoidchemical sensitivity of mucosa
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the surfactant system by using cocamidopropyl betaine, an amphoteric surfactant with a balanced HLB value, which provides effective cleaning and foaming while being milder on the oral mucosa compared to conventional anionic surfactants, thus reducing chemical irritation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The product effectively cleans teeth without damaging the enamel or gums, revitalizes and strengthens the gums, and enhances their resistance to mechanical stress, allowing for quicker regeneration and a reduced risk of irritation or bleeding during brushing.

Implementation Method 1

the polymers, in combination with the calcium glycerophosphate and the cocamidopropyl betaine, cause the formation of a microfine layer on the tooth enamel, which leads to a significant reduction in surface roughness

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 2

the two polymers create a stable and fine-pored foam that intensifies the deposition of active ingredients on the tooth enamel as well as on the gums and oral mucosa

Methodology Applied
Scientific EffectFoam formation: Foam

Data Source

PatentEP2821051B1Remineralising oral and dental hygiene and cleaning agent with gum stimulation
Publication Date: 2016.11.02 HENKEL KGAA
  • EP2821051B1 patent drawing
  • EP2821051B1 patent drawing
  • EP2821051B1 patent drawing

AI summary

Oral and dental care and cleaning products containing – by weight – 0.001 to 5 wt% calcium glycerophosphate, 0.1 to 10 wt% carboxymethylcellulose, and 0.1 to 10 wt% xanthan gum form a microfine layer on the tooth enamel, leading to a significant reduction in surface roughness. Furthermore, these products possess a stable and fine-pored foam that intensifies the deposition of active ingredients onto the tooth enamel, gums, and oral mucosa.