Topical Triterpene Composition for Stable Dermal Delivery

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Solution Overview

Problem

Existing formulations struggle to deliver and stabilize poorly water-soluble biologically active substances like pentacyclic triterpenes through the skin, leading to instability and reduced bioavailability.

Innovation Solution

A composition combining poly-n-glyceryl-sorbityl enoxolone with highly branched cyclic dextrin is used to create a stable topical delivery and release system for pentacyclic triterpenes, enhancing solubility and bioavailability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional cyclodextrins or liposomal systems are used to deliver pentacyclic triterpenes, then solubility and bioavailability are improved, but stability in formulations containing ethyl alcohol or amphiphilic substances deteriorates

Engineering Contradiction:
ImprovebioavailabilityVSAvoidformulation stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent modifies the cyclodextrin structure by introducing hydrophobic substituents at the C6 position of glucose units, changing the physical-chemical parameters of the carrier to improve compatibility with lipophilic active substances and alcohol-based formulations, thereby resolving the contradiction between bioavailability enhancement and formulation stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite system combining modified cyclodextrin with specific carriers (water, oils, waxes, alcohols, gels) to form stable formulations that maintain both the delivery efficiency for pentacyclic triterpenes and compatibility with cosmetic/pharmaceutical ingredients, particularly ethyl alcohol and amphiphilic substances

Inventive Principle:
Principle #40Composite materials

2Reliability

If liposomes or niosomes are used as release systems, then dermal absorption is facilitated, but instability occurs in the presence of protic polar solvents like ethyl alcohol

Engineering Contradiction:
Improvedermal absorptionVSAvoidvesicle stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent replaces unstable liposomal/niosomal systems with modified cyclodextrin inclusion complexes that are chemically more stable in alcohol-containing formulations, sacrificing some of the vesicle-specific benefits for overall formulation stability and compatibility with cosmetic ingredients

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

By modifying the cyclodextrin structure with hydrophobic groups, the patent changes the solubility and stability parameters of the release system, enabling it to maintain structural integrity in the presence of ethyl alcohol and amphiphilic substances while still facilitating dermal absorption

Inventive Principle:
Principle #35Parameter changes

3Reliability

If amphiphilic substances are added to improve solubility of pentacyclic triterpenes, then bioavailability increases, but structural integrity of vesicles deteriorates

Engineering Contradiction:
ImprovesolubilityVSAvoidvesicle structure
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The modified cyclodextrin acts as an intermediary carrier that solubilizes pentacyclic triterpenes through inclusion complexation without requiring additional amphiphilic substances, thereby maintaining the structural integrity of the release system while achieving the desired solubility enhancement

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively delivers and modulates the release of pentacyclic triterpenes, improving bioavailability and stability, suitable for cosmetic and pharmaceutical applications.

Implementation Method 1

Cyclodextrins have the ability to form solid inclusion complexes (host-guest complexes) with host compounds via molecular complexation. In these complexes a guest molecule is positioned inside the cavity of the cyclodextrin host.

Methodology Applied
Scientific EffectMolecular complexation: Adsorption

Implementation Method 2

The systems to topically release active substances are formulated in such a way as to deliver the active substances through the epidermis and regulate the release rate of these active substances.

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentEP4529452B1Dosage forms for topical administration of pentacyclic triterpenes
Publication Date: 2025.12.24 GIULIANI SPA
  • EP4529452B1 patent drawingFigure 1~2
  • EP4529452B1 patent drawingFigure 3~5
  • EP4529452B1 patent drawingFigure 6~7

AI summary

The invention relates to a system or composition to topically deliver and/or release a pentacyclic triterpene or an Olea europaea fruit extract titrated in maslinic and/or oleanolic acid. The delivery and release system may be contained in a cosmetic composition to be applied to skin, scalp, eyelashes, eyebrows, and nails.